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中文摘要：
本项目设计并制备了几种对电磁波有特殊相互作用的功能复合材料。通过“熵致有序”效应的调控，制备了具有磁功能的导电高分子复合微粒气溶胶材料，研究了电磁散射效应并提高了消光作用及材料的综合性能。该气溶胶对红外辐射有优异的吸收性能。从纳米微孔聚倍半硅氧烷的制备着手，得到了介电属性、力学性质均比较优良的超低介电材料，具有透波、耐温、抗湿等优良性能。为探索具有负介电常数、负磁导率的左手征材料，用晶体螺旋位错诱导，生成二维有序导电高分子纳米螺旋，具有开口的“C”环形状，探索了其自组装成二维有序的可行性。在材料制备的理论模拟及探索方面，我们用自洽场理论研究了各种拓扑和高分子结构嵌段的共聚体系，获得了相应的拓扑结构相图，及有关界面性质。采用统计物理最新研究成果“拥挤”（Jamming）理论，实现了高分子在低于Tg温度情况下的流动，为发展高分子冷加工，提出了具有创新性的方法和理论。本项目发表学术论文33篇，申请专利16项，已授权发明专利10项，其中一项专利已在企业得到应用。
结论摘要：
英文主题词electronic magnetic wave; functional material; composite material; conductive polymer; cold procession
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期刊论文
A facile strategy for controlling the self-assembly of nanocomposite particles based on colloidal st
Probing the contraction and association of polystyrene chains in semidilute solution by non-radiativ
Unusual rheological behavior of liquid polybutadiene rubber/clay nanocomposite gels: The role of pol
Structural relaxation of polystyrene glasses with dis-interpenetrated chains studied by differential
Preparation of Highly Monodisperse Hybrid Silica Nanospheres Using a One-Step Emulsion Reaction in A
Polyimide-Polydimethylsiloxane Copolymers for Low-Dielectric-Constant and Moisture-Resistance Applic
Synthesis of ordered spiral and ring-like polypyrrole nanowires in cetyltrimethylammounium bromide c
Room temperature spontaneous exfoliation of organo-clay in liquid polybutadiene: Effect of polymer e
Characterization of polymer compatibility by H-1 dipolar filter solid-state NMR under fast magic ang
Controlling the structure and morphology of monodisperse polystyrene/polyaniline composite particles
Probing chain interpenetration in polymer glasses by H-1 dipolar filter solid-state NMR under fast m
Various types of hydrogen bonds, their temperature dependence and water-polymer interaction in hydra
Synthesis of conducting polyaniline/TiO2 composite nanofibres by one-step in situ polymerization met
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