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中文摘要：
借助外力刺激动态调控荧光颜色或强度的有机压致变色材料是一类具有潜在应用前景的新型信息功能材料，但目前该领域的研究基本局限于有机小分子粉末，且其压致变色形成机理尚缺乏深入的理解。本项目拟首先合成一系列具有压致变色特性的苯乙烯腈衍生物，在保持分子间π-π共轭作用和氢键作用力相互平衡的前提下，通过在分子外围引入柔性长链等凝胶因子，利用分子自组装将苯乙烯腈类压致变色小分子制备成凝胶材料。凝胶因子的引入，在不改变压致变色特性的基础上，既可实现有机压致变色小分子的材料化，又降低了材料的荧光颜色可逆温度。项目拟借助于凝胶超分子自组装的特点，调控分子堆积方式，从而调节压致变色材料的光物理性能，深入探讨分子自组装行为- - 分子聚集态结构- - 分子变色性能之间的关联，为从分子及超分子水平揭示有机压致变色机理提供了一种新颖的研究途径。
结论摘要：
英文主题词Solid State Emission；D-A Structure；Accumulation mode；Aromatic Amine；(Thermo/Photo/Electro)-Mechanochromism
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期刊论文
Electrochemical and Electrochromic Properties of Multichromic PendriticPoly(3,6-dithienycarbazole) a
Mechanical force induced reversible fluorescence switching of two 3-aryl-2-cyano acrylamide derivati
Effect of stacking mode on the mechanofluorochromic properties of 3-aryl-2-cyano acrylamide derivati
Aggregation-Induced Emission of Z-2, 3-bis(4-(thiophen-3-yl)-phenyl)- acrylonitrile and electrochrom
Heating and mechanical force-induced luminescence on–off switching of arylamine derivatives with hig
Effects on the electrochemical and electrochromic properties of 3, 6 linked polycarbazole derivative
Effective process to achieve enhanced electrochromic performances based on poly(4,4’,4’’-tris[4-(2-b
A Multichromic Copolymer Based on 4-(9H-carbazol-9-yl)-N,N-diphenylaniline and 3,4-ethylenedioxythio
Effective process to achieve enhanced electrochromic performances basedon poly(4,4’,4’’-tris[4-(2-bi
Donor-Acceptor Cruciform π-System: High Contrast Mechanochromic Property and Multicolour Electrochro
Ferrocene-Functionalized Poly(6-(3,6-di(thiophen-2-yl)-9H-carbazol-9-yl)-hexyl Ferrocenecarboxylate)
Multicolored-Fluorescence Switching of ICT-Type Organic Solids with Clear Color Difference: Mechanic
Unique torsional cruciform π-architectures composed of donor and acceptoraxes exhibiting mechanochro
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