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中文摘要：
本项目通过设计和合成一系列具有功能性官能团（具有光和热敏感的偶氮基团；具有荧光性的基团；具有金属离子配位功能的基团）的链转移试剂（RAFT试剂）, 研究其在苯乙烯及（甲基）丙烯酸酯等单体的可逆加成断裂链转移自由基聚合(RAFT)中的控制性能, 同时合成含有功能性基团的单体，设计和合成结构精致的、分子量可控和分子量分布窄的带有功能性官能团的功能性高分子。深入研究RAFT试剂功能性结构对聚合机理、聚合控制性能以及聚合物性能的影响，考察聚合物分子量、分子量分布对聚合物性能的影响，优化RAFT试剂功能性结构和聚合条件。研究结果将为RAFT聚合的产业化应用奠定良好的基础。
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期刊论文
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期刊论文
Preparation, Characterization and Chiral Recognition of Optically Active Polymers Containing Pendent
Synthesis and photoinduced surface-relief-grating of well-defined azo-containing polymethacrylates v
Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization of Styrene in the Presence of
Synthesis and Photo-induced Birefringence and Surface-relief-gratings of Tetrazole-containing Azo Po
Preparation and Characterization of Anthracene End-Capped Polystyrene via Reversible Addition-Fragme
Atom Transfer Radical Polymerization of Styrene Using Multifunctional Iniferter Reagents as Initiato
A Novel Azo-Containing Dithiocarbamate Used for Living Radical Polymerization of Methacrylate and St
Synthesis and Characterization of Fluorescence End-Labelled Poly(styrene) via Reversible Addition-Fr
Reversible Addition-Fragmentation Chain Transfer Polymerization of 7-(4-(Acryloyloxy)butoxy) Coumari
“Living”/Controlled Polymerization of Methyl Acrylate Mediated by Dithiocarbamates under γ-Ray Irrad
Atom Transfer Radical Polymerization of Methyl Methacrylate High Efficiently Initiated by Azo-Contai
Atom Transfer Radical Polymerization of Styrene using Multi-functional Iniferter Reagents as Initiat
RAFT polymerization of styrene in the presence of 2-nonyl-benzoimidazole- 1-carbodithioic acid benzy
Preparation and Characterization of Novel Side-Chain Azo Polymer Containing Different Polar Structur
Synthesis of Dithiocarbamate Bearing Azobenzene Group and Use for RAFT Polymerization of Vinyl Monom
Atom Transfer Radical Polymerization of Styrene and Methyl Methacrylate using 2-(1-Bromoethyl)-Anthr
Synthesis of Amphiphilic ABCBA-type Pentablock Copolymer from Consecutive ATRPs and Self-assembly in
Synthesis and Self-assembly Behavior of Azobenzene-Centered (Co) Polymer via Reversible Addition- Fr
Synthesis and Self-Assembly Behaviors of Three-armed Amphiphilic Block Copolymers via RAFT Polymeriz
Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization of Vinyl Monomers Initiated b
A Novel Synthetic Method for the Well-Defined Polymer Containing Benzotriazole and Push-Pull Bisazob
Synthesis of Novel Polystyrene End-capped with Pyrene via Reversible Addition–Fragmentation Chain Tr
Nanosphere with Palladium/Polymer Composite Shells from Surface-Initiated Atom Transfer Radical Poly
“Living”/controlled Free Radical Polymerization of MMA in the Presence of Cobalt(II) 2-ethylhexanoat
Thermal Polymerization of Methyl (Meth)acrylate via Reversible Addition-Fragmentation chain Transfer
Controlled/living Radical Polymerization of Methyl Methacrylate Using Gamma Radiation as an Initiati
Influence of the Chemical Structure of Dithiocarbamates with Different R Groups on the Reversible Ad
Micrometer Tubular-shape Nanotube From Self-Assembly of Miktoarm star Amphiphilic Block Copolymers v
Inestigation into the Synthesis and Luminescent Properties of 1,2,3-Triazole Containing Copolymers v
Synthesis and Characterizations of Triphenylamine End-Functionalized Polymers via Reversible Additio
Synthesis and Characterization of Novel Copolymer Containing Pyridylazo-2-Naphthol (PAN) Unit via Re
Organic/Inorganic Hybrid Nanospheres Coated with Palladium/P4VP Shells from Surface-Initiated Atom T
Synthesis of Poly(methyl methacrylate) Labeled with Fluorescein Moieties via Atom Transfer Radical P
Synthesis of poly (vinyl acetate) with fluorescence via a combination of RAFT/MADIX and “click” chem
Controlled Synthesis and Fluorescent Properties of Poly(9-(4-vinylbenzyl)-9H-carbazole) via Nitroxid
Reversible Additional Fragmentation Chain Transfer Polymerization of Styrene under Microwave Irradia
Reversible Addition Fragmentation Chain Transfer (RAFT) Emulsion Polymerization of Methyl Methacryla
会议论文
Synthesis of Dumbbell-like Amphilic Triblock Copolymer From Consecutive RAFT Polymerization and ATRP
Design and Synthesis of Soluble Tris(8-hydroxyquinolinato)aluminum and Zinc(II) bis-(8-hydroxyquinol
Design and Synthesis of Star Polymers with Hetero-arms by the Combination of Controlled Radical Poly
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