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中文摘要：
本项研究我们在过去工作的基础上，着重通过改变配体的非配位基团来调控配位聚合物的结构与性能，探索结构与性能关系、总结其中的规律，探索其性能与应用前景。同时，努力将吸附分离性能与光电磁等性能结合起来，研究动态条件下的性能变化，为进一步研发具有实用价值的配合物多功能材料奠定了基础。在本项基金及其它基金的联合资助下，我们设计、合成和选择了多种配体，并以之与某些金属离子在常规或水热（溶剂）热条件下进行配位组装获得系列新型金属配合物，并研究了它们的有关性能，探索了结构与性能的关系，发现了一些有趣的现象及规律，在分子磁性、多孔配合物、发光配合物等研究方面取得了系列创新成果。有关研究成果已在Chem. Soc. Rev., Chem. Eur. J., Chem. Commun., Chem. Mater., Inorg. Chem.,等重要刊物发表SCI论文34篇，其中影响因子大于4.0的论文26篇，获授权中国发明专利授权10项，参编专著与教材 3部，受到同行的广泛关注和好评，在Chem. Soc. Rev. 上发表的论文当年被引用次数位列该杂志年度前8名，产生了良好影响，圆满完成了预期目标。
结论摘要：
英文主题词Complexes;construction;non-coordination group; control;relationship between structure and function
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期刊论文
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Synthesis, structure and magnetic properties of two new azido-Co-II coordination architectures: From
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