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中文摘要：
利用超分子催化体系，从结构和功能上部分模拟氢化酶活性中心活化氢及产氢的复杂过程，对于开发清洁能源和保持人类生态环境平衡及可持续发展具有重要的科学意义。本项目拟开展人工氢化酶Fe/S和Ni/Fe/S配合物的合成和催化反应的研究。1，通过对唯铁氢化酶活性中心结构的模拟，设计合成具有光活性的超分子Fe/S簇配合物，研究其光致电子转移反应及催化还原质子制氢的基本原理，为开发新型的人工氢化酶系统奠定化学基础。2，通过对镍铁氢化酶活性中心结构的化学模拟，设计合成Ni/Fe/S簇配合物，研究其催化活化氢气的机理，为开发新型燃料电池催化剂以取代铂等贵金属奠定化学基础。本项目最终的目标是利用可见光将水还原成氢气及高效的Ni/Fe/S催化剂，使我国在人工放氢酶、新型太阳能制氢和燃料电池催化剂等具有重大应用前景的高科技领域的基础研究方面达到国际领先水平。
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期刊论文
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期刊论文
Synthesis and characterization of a family of penta- and tetra-manganese(III) complexes derived from
Fe-S complexes containing five-membered heterocycles: novel models for the active site of hydrogenas
Protonation, electrochemical properties and molecular structures of halogen-functionalized diiron az
Iron(III) complexes with a tripodal N3O ligand containing internal base as a model of catechol intra
Influence of Triple Bonds as π-Spacer Units in Metal-Free Organic Dyes for Dye-Sensitized Solar Cell
Photoinduced intramolecular charge transfer and S2 fluorescence in thiophene-p-conjugated donor–acce
Azadithiolates cofactor of the iron-only hydrogenase and its PR3-monosubstituted derivatives: synthe
Protophilicity, electrochemical property, and desulfurization of diiron dithiolate complexes contain
Synthesis and Structure of a Mononuclear Co(II) Complex Based on a Salicylideneaniline Ligand, (Z)-4
Synthesis and characterization of two linear Fe-M-S clusters coordinated by bis(pyrid-2-ylmethyl)ami
Synthesis and characterization of vanadium(III) and vanadium(IV) polymers containing 3,5-pyrazoledic
Synthesis and structure of a μ-oxo diiron(III) complex with an N-pyridylmethyl-N,N-bis (4-methylbenz
An azadithiolate bridged Fe2S2 complex as active site model of FeFe-hydrogenase covalently linked to
Binuclear iron-sulfur complexes with bidentate phosphine ligands as active site models of Fe-hydroge
Diiron models for the active site of Fe-only hydrogenase with terminal organosulfur ligation: Synthe
Diiron azadithiolates with hydrophilic phosphatriaza-adamantane ligand as iron-only hydrogenase acti
Effect of deprotonation of a benzimidazolyl ligand on the redox potential and the structures of mono
Synthesis and characterization of carboxy-functionalized diiron model complexes of [FeFe]-hydrogenas
Photoinduced intramolecular charge-transfer state in thiophene-pi-conjugated donor-acceptor molecule
Photochemical H2 production with noble-metal-free molecular devices comprising a porphyrin photosens
Two Novel Carbazole Dyes for Dye-Sensitized Solar Cells with Open-Circuit Voltages up to 1 V Based o
A trimanganese cluster-based 2D layer framework with facile single-crystal -to-single-crystal transf
Aggregation of tetranuclear Mn building blocks with alkali ion. Syntheses, crystal structures and ch
Aggregation of Hexanuclear, Mixed-Valence Manganese Oxide Clusters Linked by Propionato Ligands To F
Synthesis and structure characterization of a tetranuclear manganese(III) complex: [Mn4O2(O2CMe)6(Me
[FeFe]-Hydrogenase active site models with relatively low reduction potentials: Diiron dithiolate co
Synthesis, Structure and Magnetic Properties of a Linear Trinuclear Mn(II) Complex with a Multifunct
Pentacarbonyl-12C,3C-(diphenylphosphine)(2-propyl-2-azapropane-1,3-dithiolato-1k 2S,S':22S,S')diiron
Synthesis, protonation and electrochemical properties of trinuclear NiFe2 complexes Fe2(CO)6(μ3-S)2[
(N-CnH2n-1)-1,3-Azapropanedithiolate (n=5, 6, 7)-bridged diiron complexes as mimics for the active s
Efficient near infrared D-π-A sensitizers with lateral anchoring group for dye-sensitized solar cell
Synthesis and characterization of a ladder-like coordination polymer composed of trimanganese cluste
A series of complexes with a [Mn8O8](8+) saddle-like core: Facile synthesis, crystal structure and m
Preparation, characterization and electrochemistry of an iron-only hydrogenase active site model cov
Chemical and Photochemical Water Oxidation Catalyzed by Mononuclear Ruthenium Complexes with a Negat
Photochemical hydrogen production catalyzed by polypyridyl ruthenium-cobaltoxime heterobinuclear com
Diiron models for active site of FeFe-hydrogenase with aromatic thiolate bridges: Structures and ele
Synthesis and Mechanistic Studies of Organic Chromophores with Different Energy Levels for p-Type Dy
Preparation, characteristics and crystal structures of novel N-heterocyclic carbene substituted fura
Synthesis and characterization of two cobalt complexes derived from the system containing phenylphos
Preparation, Facile Deprotonation, and Rapid H/D Exchange of the μ-Hydride Diiron Model Complexes of
Oligothiophene-2-yl-vinyl bridged mono- and binuclear ruthenium(II) tris-bipyridine complexes: Synth
Visible light driven H2 production in molecular systems employing colloidal MoS2 nanoparticles as ca
A photoelectrochemical device for visible light driven water splitting by a molecular ruthenium cata
Carbene-pyridine chelating 2Fe2S hydrogenase model complexes as highly active catalysts for the elec
Tuning the HOMO Energy Levels of Organic Dyes for Dye-Sensitized Solar Cells Based on Br_/Br3_ Elect
Effect of tetrahydroquinoline dyes structure on the performance of organic dye-sensitized solar cell
CeIV- and Light-Driven Water Oxidation by [Ru(terpy)(pic)3]2+ Analogues: Catalytic and Mechanistic S
Visible light-driven electron transfer and hydrogen generation catalyzed by bioinspired [2Fe2S] comp
Intermolecular electron transfer from photogenerated Ru(bpy)3+ to [2Fe2S] model complexes of the iro
Synthesis and characterization of two linear trinuclear complexes [M-3(CH3COO)(6)(H2O)(phen)(2)]cent
Synthesis and characterization of some new mononuclear ruthenium complexes containing 4-(un) substit
The use of phosphonates for constructing 3d-4f clusters at high oxidation states: synthesis and char
A triphenylamine dye model for the study of intramolecular energy transfer and charge transfer in dy
Structures, protonation, and electrochemical properties of diiron dithiolate complexes containing py
Pendant bases as proton transfer relays in diiron dithiolate complexes inspired by [Fe-Fe] hydrogena
Nucleophilic Attack of Hydroxide on a MnV Oxo Complex: A Model of the O-O Bond Formation in the Oxyg
Molecular Design of Anthracene-Bridged Metal-Free Organic Dyes for Efficient Dye-Sensitized Solar Ce
会议论文
Visible Light-Driven Electron Transfer and Hydrogen Generation Catalyzed by Bio-Inspired [2Fe2S] Com
Proton-hydride diiron dithiolate complexes and their reactivities relevant to the enzymatic hydrogen
Dye sensitized solar cells based organic chromophores and nanostructured TiO2 for n-type and NiO for
Synthesis and Characterization of a Linear Trinuclear Manganese(II) Complex Based on a New Type of S
Light Driven Hydrogen Production in Supramolecular Systems Based on the Active Site of [FeFe]-Hydrog
Trinuclear ruthenium supramolecue as photocatalytic assembly for visible light-driven water oxidatio
Diiron dithiolate complexes containing internal base as biomimetic models of the all-iron hydrogenas
Visible Light-Driven Electron Transfer and Hydrogen Generation Promoted by Bio-Inspired [2Fe2S] Comp
A Study on the Intramolecular Energy and Charge Ransfer of Triphenylamine dyes for Dye-Sensitized So
Solar energy conversion into hydrogen in chemical systems inspired by the active sites of photosyste
Intermolecular Electron Transfer from Photo Generated Ru(bpy)3+ to [2Fe2S] Model Complexes of the Fe
Structures, protonation, and electrochemical properties of diiron dithiolate complexes containing py
Saturated heterocycle-containing binuclear iron-sulfur complexes for the active site models of Fe-hy
Synthesis of Tyrosine-involved Corrole Cu(III) and Mn(IV) Complexes as Biomimetic Models of OEC in P
Highly efficient noble-metal-free molecular catalyst systems composed of rose bengal and cobalt bipy
Thermally Induced Aggregation of Hexanuclear Mixed-Valence Manganese Oxide Clusters Linked by Propio
Photocatalytic water reduction to molecular hydrogen catalyzed by noble-metal-free homogeneous syste
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