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中文摘要：
以分子筛为代表的无机微孔晶体材料在工业催化、吸附、分离等领域具有广阔的应用前景。有机模板剂在这类材料的合成中起着至关重要的作用，因此，"模板效应"的研究一直是无机微孔晶体合成化学的核心问题。本项目旨在温和的水热、溶剂热和离子液热体系中，利用两种有机模板剂的协同导向作用，合成一系列新颖的无机微孔晶体材料，解析其结构，系统考察在不同反应体系中，双模板剂的种类（如有机胺/有机胺、有机胺/金属配合物、离子液体/有机胺、氨基酸/有机胺等）和用量对产物晶体结构及晶化过程的影响，结合分子模拟方法，研究产物晶体结构中主-客体和客-客体间相互关系，深入理解双模板剂在合成中所起的协同模板效应，指导具有新颖结构和特殊骨架组成的无机微孔晶体材料的控制合成。
结论摘要：
英文主题词inorganic microporous crystals; synthesis;co-templates; templating effect; molecular simulation
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期刊论文
Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[
[Zn(HPO3)(C11N2O2H12)] and [Zn-3(H2O)(PO4)(HPO4)(C6H9N3O2)(2) (C6H8N3O2)]: homochiral zinc phosphite
New Lanthanide Silicates Based on Anionic Silicate Chain, Layer, and Framework Prepared under High-T
Concentrated Fluoride-medium Route to Synthesis of One-dimensional Fluoroaluminophosphate Chain (C(4
Synthesis, characterization and properties of microporous lanthanide silicates: K(8)Ln(3)Si(12)O(32)
Computational prediction of the formation of microporous aluminophosphates with desired structural f
Two new bimetallic phosphates assembled from the 4-ring building units and influence of metal on the
Na(8)CeSi(6)O(18) and Its Ti-Doped Analogue Na(8)Ce(0.73)Ti(0.27)Si(6)O(18) with Interesting Photovo
Ionothermal Synthesis and Phase Transformation of Organic-inorganic Hybrid Neutral Zincophosphate Cl
A new open-framework indium phosphate-phosphite containing intersecting extra-large 16-ring channels
Synthesis, Characterization and Phase Transformation of 3D Open-framework Zinc Phosphate [Zn-6(H2O)P
Syntheses and Characterizations of Transition-Metal-Substituted Aluminophosphate Molecular Sieves ve
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