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复杂体系相行为与分子间相互作用化学热力学研究
  • 项目名称：复杂体系相行为与分子间相互作用化学热力学研究
  • 项目类别：重点项目
  • 批准号：20633080
  • 申请代码：B0308
  • 项目来源：国家自然科学基金
  • 研究期限：2007-01-01-2010-12-31
  • 项目负责人：韩布兴
  • 负责人职称：研究员
  • 依托单位：中国科学院化学研究所
  • 批准年度：2006
中文摘要：

复杂体系相行为与分子间相互作用化学热力学研究是当今的前沿课题，本项目用量热、相平衡、偏摩尔体积、粘度、电导、紫外-可见吸收光谱、红外光谱、荧光光谱、光散射等手段，研究与超临界CO2相关的反胶束体系的相行为和分子间相互作用热力学性质，探索体系形成反胶束的条件、反胶束对水和生物分子的增溶作用及反胶束中生物分子的性质，研究这些新型反胶束体系用于生物分子提取分离、调控酶催化反应和生物纳米材料制备所涉及的热力学问题；研究不同固醇和糖脂等分子对生物膜磷脂体系热力学性质的影响、有序聚集体结构形成的基本规律及聚集体微观结构的调控，深入认识它们的生物功能；系统研究生物大分子与药物等小分子相互作用热力学性质，以及热力学性质与生物大分子的存在状态、微观结构和功能的关系。开展相关研究对于促进化学热力学及相关学科的发展、生物分子的有效利用、了解生命过程的本质和规律具有重要意义。

中文主题词： 化学热力学；复杂体系；相行为；分子间作用
结论摘要：

英文主题词Chemical thermodynamics; Complex systems; Phase behavior; Intermolecular interaction

成果综合统计
成果类型
数量
  • 期刊论文
  • 会议论文
  • 专利
  • 获奖
  • 著作
  • 79
  • 38
  • 0
  • 0
  • 0
期刊论文
Study on the conformational change of adsorbed BSA onto a moderately hydrophobic surface at differen
Molecular dynamics simulation of a carboxy murine neuroglobin mutated on the proximal side: heme dis
Hydrogen bonding interactions between a representative pyridinium-based ionic liquid [BuPy][BF4] and
利用CO2作为新型开关调控液晶和胶束之间的可逆转变
Synthesis of carbon-nanotube composites using supercritical fluids and their potential applications
Dispersion of graphene sheets in ionic liquid [bmim][PF6] stabilized by an ionic liquid polymer
Nonsynchronicity phenomenon observed during the lamellar-micellar phase transitions of 1-stearoyllys
Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propaned
两亲性分子聚集体的相变及其协同性
The hydrogen bonding interactions between the ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate
CO2-responsive TX-100 emulsion for selective synthesis of 1D or 3D gold
镍离子与酵母乙醇脱氢酶的相互作用
Acetonitrile induces nonsynchronous interdigitation and dehydration of dipalmitoylphosphatidylcholin
Reversible switching of a micelle-to-vesicle transition by compressed CO2
Stereochemistry of 4-hydroxyproline affects the conformation of conopeptides
CO2-controlled reactors: epoxidation in emulsions with droplet size from micron to nanometre scale
CO2/H2O混合绿色介质中的有机催化反应
Synthesis of graphene/polyaniline composite nanosheets mediated by polymerized ionic liquid
Unfolding and refolding details of lysozyme in the presence of β-casein micelles
Mechanism of the fast exchange between bound and free guests in cucurbit[7]uril–guest systems
Switching micellization of Pluronics in water by CO2
The dispersion of carbon nanotubes in water with the aid of very small amounts of ionic liquid
利用ＣＯ２ 作为新型开关调控液晶和胶束之间的可逆转变
Hydrogen bonding interactions in three 2-mercaptoethanol systems: An excess infrared spectroscopic s
Nonsynchronous change in the head and tail of dioctadecyldimethylammonium bromide molecules during t
Structural and kinetic properties of r-tocopherol in phospholipid bilayers, a molecular dynamics sim
Structural characterization on the gel to lquid-crystal phase transition of fully hydrated DSPC and
Enhanced stabilization of vesicles by compressed CO2
Metal-organic framework nanospheres with well ordered mesopores synthesized in ionic liquid/CO2/surf
Excess infrared absorption spectroscopy and its applications in the studies of hydrogen bonds in alc
Solvent effect on the role of methyl groups in formation of OHO hydrogen bond in dimethy
Phase diagram of androsterol-dipalmitoylphosphatidylcholine mixtures dispersed in excess water
Enhancing reaction rate of transesterification of glycerol monostearate and methanol by CO2
Synthesis of alpha-chymotrypsin/polymer composites by a reverse micelle/gas antisolvent method
Large-scale production of self-assembled SnO2 nanospheres and their application in high-performance
Effect of hydration on the CAH???O hydrogen bond: A theoretical study
α-生育酚在模型生物膜中的分子动力学模拟
CO2 capture by hydrocarbon surfactant liquids
Water-in-oil-in-water double nanoemulsion induced by CO2
Vapor-liquid equilibria of CO2 plus 1-octene plus polyethylene glycol systems
A new separation method: combination of CO2 and surfactant aqueous solutions
Solubility of CO2 in a choline chloride plus urea eutectic mixture
New topic of supercritical fluids: Local activity coefficients of supercritical solvent and cosolven
Aerobic oxidation of secondary alcohols to ketones catalyzed by cobalt(II)/ZnO in poly(ethylene glyc
DNA-mediated synthesis of microporous single-crystal-like NaTi2(PO4)(3) nanospheres
Synthesis of icosahedral gold particles by a simple and mild route
Effect of compressed CO2 on the properties of lecithin reverse micelles
Reversible switching of lamellar liquid crystals into micellar solutions using CO2
Molecular interactions between pyrazine and n-propanol, chloroform, or tetrahydrofuran
含有D 型氨基酸的新型毒肽———芋螺马芬在pH 5的溶液结构
Imidazolium cations mediated synthesis of polystyrene-polyaniline core-shell structure
New features on the phase transitions of behenic acid monolayers as unveiled by 2D-compressibility c
Liquid ordered phase of binary mixtures containing dipalmitoylphosphatidylcholine and sterols
Influence of surfactants on the morphologies of CaCO3 by carbonation route with compressed CO2
Nanoemulsions induced by compressed gases
The partition of cholesterol between ordered and fluid bilayers of phosphatidylcholine: A synchrotro
Determination and modeling of solubility of CO2 in PEG200+1-pentanol and PEG200+1-octanol mixtures
Validity and reliability of benesi-hildebrand method
Controlled fabrication of rare earth fluoride superstructures via a simple template-free route
镍离子与酵母乙醇脱氢酶的相互作用（英文）
含有D型氨基酸的新型毒肽——芋螺马芬在pH5的溶液结构
二棕榈酰磷脂酰胆碱/豆固醇脂质体液态有序相的结构性质：同步辐射X光衍射研究
Benesi-Hildebrand方程的正确性与可靠性
不同固醇与DPPC二元体系的液态有序相
A novel normalization method based on principal component analysis to reduce the effect of peak over
Formation of micelles of Pluronic block copolymers in PEG 200
Selective molecular interactions between dimethyl sulfoxide and the functional groups of 2-mercaptoe
会议论文
Properties of ionic liquids and their applications in green chemistry
Properties of green solvents and their application in green chemistry
绿色溶剂体系化学热力学性质及在绿色化学中的应用研究
Properties of ionic liquids and their applications in green chemistry
Properties of ionic liquids and their applications in green chemistry
Green solvents: Properties and applications in green chemistry
绿色化学中的化学热力学
绿色溶剂体系化学热力学及其应用研究
Recent progress in the study of phase behaviors of lipids
超临界体系化学热力学及其应用研究
从超额热力学函数到超额光谱
Study on green solvents: Thermodynamics and application in green chemistry
Green solvents: Properties and application in green chemistry
On the phase behaviors of lipid dispersions
双亲性分子聚集体相变研究新进展
固醇和维生素E对磷脂双分子膜相行为的影响
绿色介质中分子的聚集与功能调控
Applications of supercritical fluids and ionic liquids in material synthesis and chemical reactions
绿色化学中的化学热力学
超临界体系化学热力学及其在绿色化学中的应用研究
Study on supercritical fluids: Thermodynamics and their applications in green chemistry
Study on green solvents: Thermodynamics and their applications in green chemistry
Green solvents: Properties and their applications in green chemistry
Effect of compressed CO2 on reverse micelles and its application
离子液体相关微乳液体系的研究
Supercritical fluids: Thermodynamics and application in green chemistry
Phase behavior of complex supercritical fluid and ionic liquid systems
Thermodynamics of green solvents and applications in green chemistry
Supercritical fluids: Thermodynamics and application in green chemistry
Study on supercritical fluids: Thermodynamics and applications in green chemistry
Application of small angle scattering in green chemistry
On the sequential order of events as evaluated by two-dimensional correlation spectroscopy
Green solvents: Properties and application in green chemistry
超临界流体对微乳液和乳液性质的调控作用及其应用研究
Thermodynamics of CO2/reverse micellar solutions
Supercritical fluids: Properties and application in green chemistry
Properties of ILs and application in green chemistry
Study on green solvents: Thermodynamics and their applications in green chemistry
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