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中文摘要：
JACS主编Stang曾提出用12个线性双齿节点和8个类似空间坐标系的三齿节点组装成超分子单立方体，现已报道的三类例子中三齿节点均为单核金属。我们在JACS上发表了以8个四核[WS4Cu3]簇单元和12个氰根组装成含簇超分子单立方体；目前报道的多孔化合物大多是单核或双核金属与桥联配体组装的。我们以[WS4Cu4]为簇单元构成的含簇多孔超分子，对无机和有机小分子有吸附作用(Angew.Chem. Int.Ed.);Aspinall曾在Inorg.Chem.报道稀土硫醇化合物
结论摘要：
英文主题词cluster; design; assembly; structure; property
成果综合统计
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期刊论文
Formation of Four Different [MoOS3Cu3]-Based Coordination Polymers from the Same Components via Four
Two 1D coordination polymeric isomers with the same chemical formula [Cu(2,2 '-bipy)(Htda)]n: Synthe
Encapsulation of Unusual Nitrate-Water Cluster [(NO3)4(H2O)6]4- Anions into Cages of a Three-Dimensi
Solvothermal Stepwise Formation of Cu/I/S-Based Semiconductors from a Three-Dimensional Net to One-D
Hydrothermal synthesis and crystal structure of a luminescent 3D lead(II) coordination polymer [Pb(4
Syntheses, crystal structures and luminescent properties of two silver complexes of N,N,N ',N '-tetr
Assembly of a new family of mercury(II) zwitterionic thiolate complexes from a preformed compound [H
Construction of [(η5-C5Me5) WS3Cu3]-based supramolecular compounds from preformed incomplete cubane-
Mo(W)/Cu/S cluster-based supramolecular arrays assembled from preformed clusters [Et4N]4[WS4Cu4I6] a
Reactions of the pentamethylcyclopentadienyl trisulfido tungsten with M ' Cl2 (M ' = Zn, Cd, Hg): Is
Synthesis and structural characterization of two lead(II) complexes of bis(3,5-dimethylpyrazolyl)met
Construction of a novel 2D polymer [Co(dmpzm)(dca)2]∞ from reaction of a mononuclear complex [Co(dmp
Synthesis of two heterobimetallic cluster isomers [(η5-C5Me5)2Mo2(μ3-S)3S(CuI)2] and [(η5-C5Me5)2Mo2
Toward rational construction of gold, gold-silver, and gold-mercury string complexes: Syntheses, str
Constructions of a set of novel hydrogen-bonded supramolecules from reactions of cobalt(II) salt wit
Syntheses, crystal structures and third-order nonlinear optical properties of [PPh4]2[(WS4)M(μ-dppe)
Hydrothermal Synthesis and Structural Characterization of Two Zinc Coordination Polymers of 1,2-Di(4
Unique formation of two high-nuclearity metallamacrocycles from a mononuclear complex [Zn(dmpzdtc)2]
Construction of [(η5-C5Me5)MoS3Cu3]-based supramolecular assemblies from the [(η5-C5Me5)MoS3(CuNCS)3
Reactions of a tungsten trisulfido complex of hydridotris(3,5-dimethylpyrazol-1-yl)borate (Tp*) [Et4
Homo- and heterometallic coordination oligomers and polymers derived from the preformed complexes [C
Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double
Synthesis and structural characterization of a unique 3D coordination polymer [Pb(4-pya)2]n (4-pya =
Synthesis, structure and luminescent properties of a unique [WS4Cu4]-based supramolecular compound [
Formation of a 1D water chain into the channel of a unique 3D hydrogen-bound coordination polymer {[
Solvothermal synthesis and crystal structure of a luminescent 2D copper(I) coordination polymer with
Electrochemical syntheses and structures of lead(II) and bismuth(III) complexes of 4-(trimethylammon
Synthesis, crystal structure and third-order nonlinear optical properties of a hexanuclear cluster [
Protonolysis Reactions of [(Me3Si)2N]3Ln(μ-Cl)Li(thf)3 with tBuSH or EtSH: Isolation, Structures and
Assembly of [(η5-C5Me5)MoS3Cu3]-supported with single, double, triple, and quadruple one-dimensional
Construction of Symmetric and Asymmetric Mo/S/Cu Clusters from a Cluster Precursor [Et4N]2[(edt)2Mo2
Binuclear cluster-to-cluster-based supramolecular compounds: Design, assembly, and enhanced third-or
Solvent effects on the assembly of [Cu2I2]- or [Cu4I4]-based coordination polymers: Isolation, struc
Reactions of [Hg(Tab)2](PF6)2 [Tab=4-(trimethylammonio)benzenethiolate] with NaX (X = Cl, NO2, NO3):
CS2 elimination and C-S bond cleavage in [Zn(dmpzdtc)2] - Leading to formation of a cyclic octanucle
Solvothermal synthesis, structure and luminescent properties of a new 3D coordination polymer [K2Cd(
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