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新颖后过渡金属烯烃聚合催化剂和催化机理的研究
  • 项目名称：新颖后过渡金属烯烃聚合催化剂和催化机理的研究
  • 项目类别：面上项目
  • 批准号：20272062
  • 申请代码：B020203
  • 项目来源：国家自然科学基金
  • 研究期限：2003-01-01-2005-12-01
  • 项目负责人：孙文华
  • 负责人职称：研究员
  • 依托单位：中国科学院化学研究所
  • 批准年度：2002
中文摘要：

后过渡金属烯烃聚合催化剂是新一类走向工业化的单组分催化剂，是聚烯烃催化竞争的焦点课题。这类以亚胺和其它杂原子与后过渡金属形成的催化剂具有较强的变通性，其活性极大地依赖配体的立体和电子效应以及催化条件。本研究旨在设计合成新颖结构的配位催化剂，获得催化过程的中间体的结构信息，研究烯烃聚合过程中碳碳形成的机理和影响因素。

中文主题词： 金属配合物；晶体结构；乙烯聚合和齐聚；降冰片烯聚合；催化机理
结论摘要：

英文主题词metal complexes; single crystal structure; ethylene oligomerization and polymerization; norbornene polymerization; mechanism

成果综合统计
成果类型
数量
  • 期刊论文
  • 会议论文
  • 专利
  • 获奖
  • 著作
  • 39
  • 25
  • 0
  • 0
  • 0
期刊论文
Highly active vinyl-polymerization of norbornene by [2-methyl-8-(diphenylphosphino)quinoline]nickel(
Polymerization of Cyclopentadiene Initiated by Methylaluminoxane
Synthesis, Characterization and Ethylene Oligomerization and Polymerization of 2,6-Bis(2-benzimidazo
Synthesis and crystal structure of dichloro{bis[N-(4-methyl-2-pyridinyl)acetamide]}copper (II)
Vinyl-Polymerization of Norbornene Catalyzed by Bis-[N-(substituted methyl) salicylideneiminato]nick
Ethylene Oligomerization by Hydrazone Ni(II) Complexes / MAO
Synthesis, Characterization and Ethylene Oligomerization of 2,6-Bis(imino) phenoxy Cobalt Complexes
Bis(2,6-(2’,6’-diisoproylanil)diformyl-4-chlorophenolate)nickel(II)
Syntheses and X-ray Structures of New Phenoxy Imino Compounds
Ethylene Oligomerization by 8-Aminoquinoline Nickel Dichloride Complex Supported on b-Cyclodextrin
Synthesis and characterization of dibenzofuran derivatives
Silica-Supported Nickel and Zirconium Catalysts for Branched Polyethylene
Preparation of Novel PE-grafted-4-vinylpyridine-Supported Metallocene Catalysts for Ethylene Polymer
Vinyl Polymerization of Norbornene with Neutral Salicylaldiminato Nickel(II) Complexes
Synthesis and characterization of 2-imino-indole nickel complexes and their ethylene oligomerization
Combined Polymerization Catalysis of Late-transition Metal Complex and Zirconocene for Branched Poly
Influence of Electronic Effect on Catalytic Activity of Salicylaldiminato Nickel (II) Complexes
双水杨醛亚胺双核镍(II)配合物降冰片烯加成聚合的研究
Bimodal Polyethylene Promoted by Novel Nickel Complex
Pd催化P-C偶联合成膦配体的进展
酰腙钛配合物的合成及其催化乙烯聚合研究
Synthesis and Characterization of N-(2-pyridyl)benzamide-Based Nickel Complexes and Their Activity f
Influence of electronic effect on catalytic activity of bis(imino)pyridyl Fe (II) and bis(imino)pyri
Supramolecular Helical Architecture Assembled by Double-Helical [Ag2L2] Units
Synthesis and Crystal Structure of Bis-{N-[2-(6-ethylpyridyl)]-Salicylideneiminato}Cobalt(II)
Synthesis, Characterization and Ethylene Oligomerization and Polymerization of 2-Ethylcarboxylate-6-
Preparation and Characterization of Carboximidate Iron (II) Complexes
Synthesis and characterization of 2-ethylcarboxylate-6-iminopyridyl nickel (II) complexes and their
Bridged Bis-pyridinylimino Dinickel(II) Complexes: Syntheses, Characterization, Ethylene Oligomeriza
后过渡金属配合物催化乙烯齐聚与聚合的研究进展
Preparation and characterization of acylhydrazone nickel (II) complexes and their catalytic behavior
Syntheses of benzimidazoles, quinoxalines and 3,3-Dihydro-1H-1,5- benzodiazepines starting from o-Ph
Synthesis and characterization of {2-formyl-6-[1-(2,4,6-trimethylphenyl)]-4- chlorophenoxy}2Ni and i
Nickel(II) complexes bearing phosphinooxazoline ligands: synthesis, structures and their ethylene ol
Synthesis and characterization of bis-[2-[[(2-alkoxyphenyl)imino] methyl]phenolato-O,N,O]nickel(II)
α-芳香亚胺-2-乙基-6-乙酯基吡啶金属配合物及其烯烃聚合催化研究
Synthesis and Characterization of New bis(1-Aryliminomethylenyl naphthalen-2-oxy)nickel complexes an
Iron Complexes Bearing 2-Imino-1,10- phenanthrolinyl Ligands as Highly Active Catalysts for Ethylene
Synthesis and Characterization of Tridentate Nickel Complexes Bearing P^N^N and P^N^P Ligands and Th
会议论文
Ethylene polymeriZation by Novel Nickel Catalysts
Weak Bonds in Spontaneous Association of Complexes and Catalysis
新颖镍配合物乙烯齐聚和聚合催化
Syntheses and Characterization of Novel Nickel Complexes
The Merit of Late-Transition Catalysts in Ethylene Activation
Ethylene Oligomerization and Polymerization Promoted by 2,6-Bis(2-benzimidazolyl)pyridylchromium chl
Olefin Polymerization by 2-Carboxylate-6-iminopyridyl Palladium Complexes
Polymerization of Cyclopentadiene Initiated by Methylaluminoxane
Vinyl Polymerization of Norbornene Over Supported Nickel Catalyst
Transition-Metal Complexes Ligated with 2-Imino-1,10-phenanthrolinyl Ligands for Ethylene Activation
Late-Transition Metal Catalysts for Long-Chain Olefins and Branched Polyethylene
The potential of Late-Transition Metal Catalysts in Ethylene Polymerization
MgCl2-Supported Nickel Catalysts for Norbornene Polymerization
新型乙烯聚合和齐聚的后过渡金属催化剂
含吡啶单亚胺配体的铁(Ⅱ)、钴(Ⅱ)配合物的合成及乙烯催化性能
Nickel Complexes as Catalysts for Branched Polyethylene
N-(2-吡啶)苯甲酰胺衍生物镍配合物的乙烯齐聚催化及三苯基膦对催化活性的影响
α-芳香亚胺-2-乙基-6-乙酯基吡啶金属配合物及其烯烃聚合催化研究
双吡啶亚胺双核镍配合物的合成、表征及其乙烯催化性能的研究
Ethylene Polymerization Promoted by Nickel Complexes
New Bidentate Ferrous Complexes as Catalysts for Ethylene Polymerization
Nickel (II) Complexes bearing 2-Ethylcarboxylate-6-iminopyridine ligands for Ethylene Oligomerizatio
Methylalumoxane initiated polymerization of cyclopentadiene and the hydrogenation of polycyclopentad
铁配合物催化的乙烯聚合与齐聚
新型钯烯烃催化剂的合成和结构
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