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中文摘要：
通过分子设计，合成同时含高效猝灭荧光光敏基团及可水解硅源部分的新型功能化过渡金属铂(Pt)配合物。通过取代基的调节实现配合物的长波段激发， 以此消除由于待分析物、基质及仪器背景所造成的干扰。利用模板剂的结构导向作用实现孔道结构的微调和功能分子在孔道内的共价嫁接，制备出以价廉易得的Si-O网络结构作为基本骨架的介孔氧气传感材料。通过有机/无机杂化组分之间的强力Si-C共价健合，解决目前溶解氧测定过程中所面临的磷光配合物脱附所导致的流失难题，实现发光分子在基质中的均匀分布，显著改善该类复合杂化材料的光热稳定性，提高材料的使用寿命。在此基础上深入系统地研究其对氧气的敏化性能，为过渡金属掺杂有机/无机杂化氧气传感材料的研究和开发开辟新的途径。本研究可加深对氧气/配合物相互作用机理的理解和认识，有望开发出新一代拥有自主知识产权、性能优良的有机/无机共价嫁接高效氧气传感复合材料。
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期刊论文
Effect of Oxygen Vacancy on Phase Transition and Photoluminescence Properties of Nanocrystalline Zir
Characterization and Photoluminescence Properties of Eu3+ Doped 3CdO-Al2O3-8SiO2 Amorphous System fo
Synthesis, structures, and photophysical properties of fluorine-functionalized yellow-emitting iridi
Preparation and Photoluminescence Properties of Bidentate Ligand Containing Electro-transporting Gro
Luminescence and oxygen sensing properties of ORMOSILs covalently grafted with a novel ruthenium(II)
A New Blue-emitting Diimine Copper(I) Complex: Synthesis, Crystal Structure and Photophysical Proper
Improved photoluminescence properties of a novel europium(III) complex covalently grafted to organic
Effect of organic modification on oxygen sensing properties of xerogel with a covalently linked ruth
Reduced Efficiency Roll-Off in Organic Light-Emitting Diodes by a Novel Short-Lived Organoeuropium E
Realization of High-Energy Emission from [Cu(N-N)(P-P)](+) Complexes for Organic Light-Emitting Diod
Preparation, characterization, and luminescence properties of novel hybrid material containing europ
Low-voltage, high-ef?ciency nondoped phosphorescent organic
light-emitting devices with double-quant
Highly sensitive oxygen sensors based on Cu(I) complex-polystyrene composite nanofibrous membranes p
Electrospinning preparation and characterization of a new kind of composite nanomaterials: One-dimen
A series of 4,5-diazafluoren-9-one-derived ligands and their Cu(I) complexes: Synthesis, characteriz
Electrospinning preparation and photophysical properties of one-dimensional (1D) composite nanofiber
A Saturated Red-Emitting Phosphorescent Iridium(III) Complex for Application in Organic Light Emitti
A bright blue emission material based on anthracene: Synthesis, characterization and luminescent pro
Synthesis, Characterization, and Luminescent Properties of Europium Complexes with Fluorine Function
Synthesis, photophysical and oxygen-sensing properties of a novel bluish-green emission Cu(I) comple
A Series of Cu-I Complexes Containing 1,10-Phenanthroline Derivative Ligands: Synthesis, Characteriz
Synthesis, photophysical and oxygen-sensing properties of a novel Eu3+ complex incorporated in mesop
A highly selective regenerable optical sensor for detection of mercury(II) ion in water using organi
Enhanced efficiency and reduced roll-off in nondoped phosphorescent organic light-emitting devices w
Synthesis and characterization of new bifunctional nanocomposites possessing upconversion and oxygen
Synthesis, characterization, and oxygen sensing properties of Ru(II) complex covalently grafted to m
High-Performance Oxygen Sensors Based on Eu(III)
Complex/Polystyrene Composite Nanofibrous Membranes
Optical oxygen sensing materials based on a novel dirhenium(I) complex assembled in mesoporous silic
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