欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
位置：立项数据库 > 立项详情页
中文摘要：
"活性"/可控自由基聚合由于其相对于其它活性聚合而言具有聚合条件温和、适用的单体面广等特点而备受关注。它主要包括Iniferter法、SFRP、ATRP以及RAFT聚合等方法。为了探索这些方法之间存在着内在的联系，本项目在前期探索性工作的基础上，通过向热引发条件下的RAFT聚合（或iniferter聚合）体系中加入ATRP催化剂，考查添加前后聚合速率的变化以及聚合的"活性"/可控特征。通过使用不同的单体、不同结构和性能的RAFT试剂（Iniferter试剂）、ATRP金属盐和配体，考察从RAFT聚合（或iniferter聚合）转变为ATRP聚合的条件和影响因素，深入理解ATRP、Iniferter以及RAFT"活性"自由基聚合机理间的内在联系，研究聚合机理转变的条件和规律，发展可控产物结构的聚合反应和聚合方法，丰富"活性"自由基聚合的研究。
结论摘要：
英文主题词mechanism transfer; ATRP; RAFT; Iniferter; radical polymerization
成果综合统计
期刊论文
会议论文
专利
获奖
著作
期刊论文
Universal Xanthate-Mediated Controlled Free Radical Polymerizations of the "Less Activated" Vinyl Mo
Synthesis of Miktoarm Dumbbell-Like Amphiphilic Triblock Copolymer by Combination of Consecutive RAF
Preparation of Miktoarm Star-Block Copolymers PS(n)-b-PVAc(4-n) via Combination of ATRP and RAFT Pol
SET-RAFT Polymerization of Progargyl Methacrylate and a One-Pot/One-Step Preparation of Side-chain F
Iron-Mediated ICAR ATRP of Styrene and Methyl Methacrylate in the Absence of Thermal Radical Initiat
Chlorodithiocarbamate-Mediated RAFT Polymerization: A Novel Synthetic Method for ATRP Macroinitiator
Synthesis of Miktoarm Star Amphiphilic Block Copolymers via Combination of NMRP and ATRP and Investi
Single Electron Transfer-Living Radical Polymerization of Methyl Methacrylate in Fluoroalcohol: Dual
A combination of RAFT and "Click" chemistry techniques to synthesize polymeric europium complexes wi
Preparation and characterization of poly(styrene)/metal composites via reversible addition-fragmenta
Controlled Synthesis of pH-Responsive Amphiphilic A(2)B(2) Miktoarm Star Block Copolymer by Combinat
Single-Electron Transfer Living Radical Polymerization (SET-LRP) of Methyl Methacrylate (MMA) with a
相关项目
朱秀林的项目