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中文摘要：
通过稀土金属三氟甲磺酸盐催化的酚醛缩合反应，高选择性地合成第三代超分子主体化合物――杯芳烃。通过特定的方法，选择性地对该杯芳烃进行修饰，首次合成具有特定结构的新型超分子化合物――双环杯芳烃，并对杯芳烃进行识别，探索该主体化合物与不同离子或分子客体的结合能力，建立超分子主体化合物的结构和配位能力的关系。研究超分子配体的催化性能，将超分子用于催化小分子间的化学反应，并利用其催化特性，提高小分子反应的选择性、收率等，增加化学反应的原子经济性，使原子利用率达到最大化。项目的实施将丰富和发展有机合成新方法，为第三代超分子主体化合物的合成、识别和催化性能研究提供了一条绿色的途径，并拓展了超分子化学的研究领域。
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期刊论文
Ytterbium(III) triflate catalyzed one-pot synthesis of 1,3-thiazolidin-2-imines from epichlorohydrin
Strontium(II) triflate catalysed condensation of beta-naphthol, aldehyde and urea or amides: a facil
A SIMPLE AND EFFICIENT PROCEDURE FOR THE BECKMANN REARRANGEMENT OF OXIME USING bis-(TRICHLOROMETHYL)
Copper(II) Acetate Catalyzed Cross-Coupling of Pentafluorophenylboronic Acid with Amines under an At
Dramatically accelerated addition under solvent-free conditions: An efficient synthesis of (E)-1,2,4
A Novel Procedure for the Synthesis of Benzo[b][1,8]naphthyridine-3-carboxylate Derivatives from Mor
Regioselective Synthesis of 5H-Thiazolo[3,2-a]pyrimidin-5-ones from Morita-Baylis-Hillman Adduct Ace
First Vilsmeier-Haack Synthesis of Flavones using bis-(Trichloromethyl) Carbonate/Dimethylformamide.
A novel and efficient synthesis of bis(benzofuranyl)methanes and 2-benzofuran-1-nitroalkanes catalyz
An efficient synthesis of 2-hydroxy- 7,8-dihydroquinolin-5(6H)-ones and 7,8-dihydroquinoline-2,5(1H,
Strontium triflate catalyzed one-pot condensation of beta-naphthol, aldehydes and cyclic 1,3-dicarbo
Ytterbium triflate hydrate catalyzed Michael addition and cyclocondensation of alpha,beta-unsaturate
An efficient method for the synthesis of dialkyl chlorophosphates from trialkyl phosphites using bis
Sc(OTf)(3)-Catalysed ring-opening of aziridines with phenol derivatives under solvent-free condition
Solubility of Tiamulin Hydrogen Fumarate in Acetone, Acetonitrile, Ethyl Acetate, Ethyl Formate, and
The cyclisation of 2 '-aminochalcones using silica-supported Yb(OTf)(3) under solvent-free condition
An efficient synthesis of 3-arylmethyl-7,8-dihydro-6H-chromene-2,5-diones from Baylis-Hillman adduct
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