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中文摘要：
通过设计合成若干种多氮杂环阳离子有机模板剂进行分子组装，获得结构新颖的原子簇超分子互穿体系，主要包括过渡金属硫簇复合物，多酸氧簇复合物等和过渡金属卤簇复合物。从微观上探究无机聚合结构与反应原料的定性/定量关系以及无机骨架与模板阳离子之间的精细相互作用机理，通过超分子组装的方法来改善无机簇合物材料的理化性能。把无机类分子强的刚性和有机芳香分子好的可调节导向性结合起来，综合利用无机硫簇体系优良的反饱和吸收性能和多酸氧簇的结构易修饰性，制备具有大的非线性光学极化系数或好的催化性等综合性能的复合晶态材料，使簇合物超分子类功能材料的开发获得关键性进展。突出意义基于原子簇类分子最重要的优点为其多功能性和结构易调性，通过引进氮杂环模板离子进行微扰来试图得到结构新颖的超分子缠结物，并探讨其光学性质和催化性能。这种有机/无机超分子互穿体系的合成也是多学科交叉的一个崭新尝试。
英文摘要：
Nitrogen-containing heterocyclics；Organic template；Interpenetrating structure；Orientation construction；Property
结论摘要：
本项目通过设计合成若干种多氮杂环阳离子有机模板剂进行分子组装，获得了多个系列结构新颖的原子簇超分子互穿体系，主要包括过渡金属硫簇复合物，多酸氧簇复合物和过渡金属卤簇复合物等。从微观上探究了无机聚合结构与反应原料的定性/定量关系以及无机骨架与模板阳离子之间的精细相互作用机理，发现了重要的取代基支链效应，通过超分子组装的方法改善了无机簇合物材料的理化性能。把无机类分子强的刚性和有机芳香分子好的可调节导向性结合起来，制备出了具有良好的光催化性等综合性能的复合晶态材料，使簇合物超分子类功能材料的开发获得了关键性的进展。突出意义基于原子簇类分子最重要的优点为其多功能性和结构易调性，通过引进氮杂环模板离子进行微扰得到了多个系列结构新颖的超分子缠结物，并探讨其光学性质和催化性能。这种有机/无机超分子互穿体系的合成也是多学科交叉研究的一个成功范例。
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期刊论文
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Hydrothermal Syntheses, Crystal Structures, and Thermal Gravimetric Analysis (TGA) of Two Inorganic-
Subtle side chain effect of methyl substituent on the self-assembly of polypseudorotaxane complexes:
Syntheses and Crystal Structure of Three Novel Supramolecular Halides/Pseudohalides {(DMB) [Cu-2(SCN
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Three Novel Metal Supramolecular Polymers Directed by 1,2-bis(pyridinium)ethane Cation: Syntheses an
Construction and isomer recognition of polyoxometalates functionalized by 1,2-dimethylimidazole alka
Templated fabrication, isomer recognition of series of 1,1′-(alkane-1,ω-diyl)-bis(3-methylimidazoliu
Three unprecedent polycational templated cuprous thiocyanate networks: synthesis, structure, and pro
Synthesis and Structural Characterization of Cation-Induced Complex: [Cd-4(SCN)(6)(BPB)](n) With One
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Syntheses, Crystal Structures of Five Supramolecular Halides/Pseudohalides: (BPP)[CdI4], (BPP)[HgBr4
C-C Oxidative Coupling Reaction of Ethylene-Bridged Azoles via Double C-H Activation With the Cataly
Synthesis and Structure of a Supramolecular Coordination Polymer [ZnI2L(CH3OH)(H2O)(2)](n) (L = N-(3
Synthesis and Characterization of Two New Polymolybdate Clusters Containing Chlorine Based on Mo-POM
An unprecedented iota-type octamolybdate: [TbI1](2)[(beta-Mo8O26)(0.5)(iota-Mo8O26)] directed by a n
pH-dependent assembly of metal-organic hybrid compounds based on octamolybdates and a new flexible m
A Novel Twin-Nest-Shaped Supramolecular Cluster Compound [Et3N(n-Bu)](4)[(Mo2O2S6Cu6I6)]: Synthesis,
Synthesis and Structure of a HgCl2 Coordination Polymer With 1,4-Bis(benzimidazole-1-yl-methylene)be
Syntheses and Crystal Structures of Two Inorganic-Organic Hybrid Materials: [BDMLPX](3)[Mo8O26](2)[H
Three silver (I) supramolecular compounds constructed from pyridinium or methylimidazolium polycatio
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Synthesis, Structures and Photocatalytic Properties of Two Novel Ag(I) Polymers Directed by 1,3-Bis(
Synthesis, crystal structures and sensitivity to sunlight of two Ag (I) photoresponsive metal-organi
Novel bis(methylimidazolium) alkane bolaamphiphiles as templates for the construction of halocluster
Hydrothermal Synthesis and Crystal Structure of a Novel Supramolecular Coordination Polymer {[Cu (bp
Syntheses, Structure, Photoluminescent, and Thermal Properties of a Novel Coordination Polymer [CuI(
The anion exchange reaction of bis(isoquinoline) ionic liquids: self-assembly, crystal structures an
Five hybrid thiocyanate networks oriented by polyvalent cationic templates: Synthesis, structure and
Bis(imidazole) Cation Templates and Subtle Effect: Syntheses and Characterization of Three New Pb(II
Crystal structures and photocatalytic properties of two novel iodoplumbate hybrids templated by mult
Fabricating roughened surfaces on halloysite nanotubes via alkali etching for deposition of high-eff
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