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中文摘要：
项目实施以来取得的主要创新性研究结果包括1.设计合成了若干不同类型三蝶烯衍生的新型主体分子，系统研究了它们的分子识别与组装性能，建立和发展了一系列具有结构与功能特色的三蝶烯超分子体系，尤其是具有可调控性质的超分子化学新体系，同时揭示了三蝶烯基元在新型大环主体分子体系构建中的特殊作用。2.基于酰肼与酰胺基脲合成子，发展了一类新型多氢键双分子带组装体系，并发现该类组装体的双螺旋结构特征、动态组装过程以及有机凝胶等性质，此外，报道了首例非杂环氢键自组装环型六聚体及其超分子手性性质。3.研究了邻菲咯啉芳酰胺螺旋折叠体的形成与酸碱调控开关性质，构建了首例基于芳酰胺型的Helix-Turn-Helix超二级结构折叠体，并首次发现蒽醌衍生的邻菲咯啉芳酰胺折叠体具有螺旋诱导的选择性催化氢化性质。4.发展了一种合成与拆分固有手性杯芳烃的方便、有效的新方法，同时基于杯芳烃，还发展了一系列分子识别与组装新体系。
结论摘要：
英文主题词hosts; design and synthesis; structure; molecular recognition; molecular assemblies
成果综合统计
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期刊论文
A highly efficient and selective turn-on fluorescent sensor for Cu2+ ion based on calix[4]arene bear
Inherently Chiral Calix[4]arene-Based Bifunctional Organocatalysts for Enantioselective Aldol Reacti
Efficient Potassium Ions Templated Synthesis and Controlled Destruction of [2]Rotaxanes Based on Cas
An Effective Hg2+-selective Fluorescent Chemosensor Based on a Calix[4]arene Bearing Four Dansyl Ami
Mutual Responsive Hydrazide-Based Low Molecular-Mass Organic Gelators: Probing Gelation on the Molec
Chiral Induction in Phenanthroline-Derived Oligoamide Foldamers: An Acid and Base Controllable Switc
Complexation of Triptycene-Based Macrotricyclic Host Towards (9-Anthracylmethyl)-benzylammonium Salt
Novel Anthracene-Based Cylindrical Macrotricyclic Polyether: Powerful Host for Bispyridinium Dicatio
Novel Anion-Tuning Supramolecular Gels with Dual-Channel Response: Reversible Sol-Gel Transition and
Triptycene-derived oxacalixarene with expanded cavity: synthesis, structure and its complexation wit
Efficient synthesis and resolution of meta-substituted inherently chiral aminocalix[4]arene derivati
Synthesis and analysis of hydroxyl substituted triptycene adducts: the competitive recognition betwe
Isomeric Squaraine-Based [2]Pseudorotaxanes and [2]Rotaxanes: Synthesis, Optical Properties and Thei
Self-Assembled Interwoven Cages from Triptycene-Derived Bis-Macrotricyclic Polyether and Multiple Br
Stabilizing G-Quadruplex DNA by a Scissors-Shaped Binaphthyl Derivative through the Entangling Mode:
Assembly of a Self-Complementary Monomer: Formation of Supramolecular Polymer Networks and Responsiv
Triptycene Derived Oxacalixarenes as New Wheels for Synthesis of [2]Rotaxanes: Acid-Base and Metal I
Aromatic single-walled organic nanotubes self-assembled from NH-bridged azacalix[2]triptycene[2]pyri
Structure-property relationship of a class of efficient organogelators and their multistimuli respon
Supramolecular Substitution Reactions Between Hydrazide-Based Molecular Duplex Strands: Complexation
Noncovalent Synthesis of Shape-Persistent Cyclic Hexamers from Ditopic Hydrazide-Based Supramolecula
Synthesis and structures of novel enantiopure inherently chiral calix[4]arene-derived salphen ligand
Synthesis, structures and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and
Enantiopure inherently chiral calix[4]arene derivatives containing quinolin-2-yl-methanol moiety: sy
Probing the Dynamic Environment-Associated Conformational Conversion from Secondary to Supersecondar
Paraquat guest induced hydrogen-bonding modes of a hydrazide-derived bis(meta-phenylene)-32-crown-10
Formation of Ternary Complexes Between a Macrotricyclic Host and Hetero-Guest Pairs: An Acid-Base Co
Helical Molecular Duplex Strands: Multiple Hydrogen-Bond Mediated Assembly of Self-Complementary Oli
A New Approach to Enantiopure Inherently Chiral Calix[4]arenes: Determination of Their Absolute Conf
Quadruply Hydrogen Bonded Building Block from Hydrazide-Quinolinone Motif and Gelation Ability of It
Selective Templated Complexation of Cylindrical Macrotricyclic Host with Neutral Guests: Three Catio
Synthesis of a novel triptycene-based molecular tweezer and its complexation with paraquat derivativ
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