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多功能"一体化"新型大分子Lewis酸催化剂的合成及其催化性能研究
  • 项目名称：多功能"一体化"新型大分子Lewis酸催化剂的合成及其催化性能研究
  • 项目类别：面上项目
  • 批准号：20876147
  • 申请代码：B060409
  • 项目来源：国家自然科学基金
  • 研究期限：2009-01-01-2011-12-31
  • 项目负责人：苏为科
  • 负责人职称：教授
  • 依托单位：浙江工业大学
  • 批准年度：2008
中文摘要：

以简单易得的物质为起始原料，通过可调控有机合成及"嫁接技术"，将"Lewis酸性"和"手性"进行有效"捆绑"，制备以杯芳烃为母体的多功能"一体化"新型可回收催化剂-一系列具有较高催化活性和高度立体选择性的手性杯芳烃基磺酸盐。解决传统催化体系中存在的催化剂和手性配体难回收问题，实现两者的同步回收，避免稀有资源的流失。将此类新型"捆绑式"多功能手性催化剂用于小分子间的Aldol、Michael等反应，研究其催化活性、立体选择性及"边臂"效应。课题的实施将丰富和发展有机合成及不对称合成新方法，拓展催化剂功能点的"嫁接技术"，实现催化剂的多功能化和功能团的一体化，并为某些立体选择性反应提供一条可借鉴方法。

中文主题词： 多功能，一体化，大分子催化剂，立体选择性
结论摘要：

英文主题词binding; multifunctional; reusable; assymmetric synthesis

成果综合统计
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  • 期刊论文
  • 会议论文
  • 专利
  • 获奖
  • 著作
  • 44
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期刊论文
Mechanically activated synthesis of 1,3,5-triaryl-2-pyrazolines by high speed ball milling
Mechanically Activated Solid-State Synthesis of Flavones by High-Speed Ball Milling
The cyclisation of 2 ';-aminochalcones using silica-supported Yb(OTf)(3) under solvent-free conditio
A facile synthesis of flavones catalysed by gallium(III) triflate
Efficient One-Pot Condensation of beta-Naphthol, Aldehydes, and Cyclic 1,3-Dicarbonyl Compounds Cata
A Practical and Efficient Vilsmeier Synthesis of 3-Chloroindole-2-carboxaldehydes
Recent Progress in the Use of Vilsmeier-Type Reagents
Mild and efficient method for synthesis of Eaminones using Ytterbium Triflate as Catalyst
New Vilsmeier reaction for facile synthesis of 4-phenyl-2,4-dihydrochromeno[4,3-c]pyrazoles with bis
Selective synthesis of "paco" or "alt" isomers of acetoxylcalixarenes catalysed by Bi(OTf)(3)
A Novel and Efficient Reaction of Imidazolidin-2-one and N-Acylbenzotriazoles: A Facile Synthesis of
Aromatization of 1,3-Cyclohexanediones Mediated by bis-(Trichloromethyl) Carbonate/DMF System
Intramolecular Cyclization of 2 ';-Aminochalcones by Halomethyleniminium Salts Derived from BTC/DMF
Ytterbium triflate catalysed Friedel-Crafts reaction using carboxylic acids as acylating reagents un
Novel Synthesis of 2,4-Dihydro-5-amino[1,2,4]triazol-3-ones from 1,3-Disubstituted Thioureas
Cu(OTf)(2)/Et(3)N-promoted cyclocondensation of activated alpha-methylene alkenes and nitroolefins:
Novel synthesis of 6,12-dihydroindolo[3,2-b]carbazoles catalysed by p-toluenesulfonic acid
MICROWAVE-ASSISTED, Yb(OTf)(3)/TfOH COCATALYZED SYNTHESIS OF XANTHONES AND THIOXANTHONES BY INTRAMOL
A Continuous Kilogram-Scale Process for the Manufacture of 7-Ethyltryptophol
Synthesis of 2,4-diarylquinolines: nickel-catalysed ligand-free cross-couplings of 4-chloro-2-arylqu
Mechanochemical-assisted efficient extraction of rutin from Hibiscus mutabilis L.
Basic Ionic Liquid as Catalyst for the Efficient and Green Synthesis of 2-Amino-3-nitrobenzonitriles
A CONVENIENT METHOD FOR SYNTHESIS OF 5-CHLORO-2-ARYLOXAZOLE-4-CARBALDEHYDE WITH VILSMEIER REAGENT
An approach to synthesis of (Z)-2-chloro-1,3-diarylpropen-1-ones by Vilsmeier reagent (bis-(trichlor
Solvent-Free Cross-Dehydrogenative Coupling Reactions under High Speed Ball-Milling Conditions Appli
A new approach to the synthesis of 2,6-dichloro-3-fluorobenzonitrile: a useful pharmaceutical interm
A novel sulfonic acid functionalized ionic liquid catalyzed multicomponent synthesis of 10,11-dihydr
Direct Benzylic Oxidation with Sodium Hypochlorite Using a New Efficient Catalytic System: TEMPO/Co(
Efficient and selective extraction of magnolol from Magnolia officinalis by mechanochemical extracti
A Convenient Method for the Synthesis of 3,5,6-Trisubstituted-2-chloropyridines with bis-(Trichlorom
Ytterbium (III) triflate catalysed [3+2] cycloaddition involving isothiocyanates and epichlorohydrin
Recent Developments in the Use of bis-(Trichloromethyl) Carbonate in Synthesis
First Vilsmeier-Haack Synthesis of Flavones using bis-(Trichloromethyl) Carbonate/Dimethylformamide
Microwave-assisted novel synthesis of amino-thieno[3,2-b]pyridines under solvent-free conditions
SYNTHESIS AND BIOLOGICAL ACTIVITIES OF NEW CHIRAL IMIDAZOLINONE DERIVATIVES
Unexpected and Divergent Reactions of N-Formyl-1,2-dihydroquinolines with Sodium Azide: Highly Chemo
Imidazolethiones: novel and efficient organocatalysts for asymmetric Friedel-Crafts alkylation
Solubility of Avermectin B(1a) in Some Pure and Mixed Solvents from (278.2 to 318.2) K
SYNTHESIS OF 1-AZAXANTHONES AND 1-AZATHIOXANTHONES BY Yb(OTf)(3)/TfOH CO-CATALYZED INTRAMOLECULAR FR
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