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多原子分子体系动力学研究
  • 项目名称：多原子分子体系动力学研究
  • 项目类别：重点项目
  • 批准号：20433080
  • 申请代码：B0304
  • 项目来源：国家自然科学基金
  • 研究期限：2005-01-01-2008-12-31
  • 项目负责人：唐紫超
  • 负责人职称：研究员
  • 依托单位：中国科学院化学研究所
  • 批准年度：2004
中文摘要：

利用电喷雾技术、低温冷却和低温基质隔离技术等与超快时间分辨光电子能谱技术、时间分辨红外光谱等相结合的新的实验手段和方法，在气相条件下深入研究多原子分子(包括自由基)及分子团簇体系解离电离过程、能量重新分配和非绝热过程和电子和离子溶剂化动力学过程；以及在凝聚态或惰性基质隔离条件下，分子和离子于低温环境中在溶剂或基质影响下结构特征及物化性质和反应等。本项目将通过多种手段，多角度和多层面的研究和探讨复杂

中文主题词： 多原子分子体系动力学超块时间分辨溶剂化环境影响
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期刊论文
The laser-induced fluorescence spectroscopy of CoF in the ultra violet region.
Coordination of niobium and tantalum oxides by Ar, Xe and O2: Matrix isolation infrared spectroscopi
Remarkable Dinitrogen Activation and Cleavage by the Gd Dimer: From Dinitrogen Complexes to Ring and
On the vibrations of N2O trapped in solid para-hydrogen.
Experimental and theoretical investigation on binary semiconductor clusters of Bi/Si, Bi/Ge, and Bi/
A study on a new 2[Delta] Rydberg state of SF by resonance-enhanced multiphoton ionization spectrosc
Formation and Characterization of the Photochemically Interconvertible Side-On and End-On Bonded Dio
Phenyl-Coinage Metal (Ag, Au) Complexes: an Anion Photoelectron Spectroscopy and Density Functional
F2S+- - X2S+ Band System of Cobalt Carbide
Matrix isolation infrared spectroscopic and theoretical study of the BNNO and AlNNO molecules.
Reactions of Gadolinium Atoms and Dimers with CO: Formation of Gadolinium Carbonyls and Photoconvers
Apparatus for High-Resolution Solid Hydrogen Matrix Isolation Spectroscopy and its Application.
Vibrational spectroscopy of N2O in solid neon matrices.
Experimental and theoretical studies on carbon-nitrogen clusters C2nN7.
Reactions of platinum cluster ions with benzene.
Identification of new bands in the red system of CoO.
Matrix Isolation Infrared Spectroscopic and Theoretical Study of NgMO (Ng = Ar, Kr, Xe; M = Cr, Mn,
Reactions of Early Lanthanide Metal Atoms (Nd, Sm, Eu) with Water Molecules. A Matrix Isolation Infr
Coordination of ScO+ and YO+ by Multiple Ar, Kr, and Xe Atoms in Noble Gas Matrixes: A Matrix Isolat
Noble Gas-Transition Metal Complexes: Coordination of ScO+ by Multiple Ar, Kr, and Xe Atoms in Noble
Infrared Spectra of the OH+ and H2O+ Cations Solvated in Solid Argon.
Formation of the end-on bonded OTiNN dinitrogen complex and its photoconversion to the side-on bonde
Matrix Isolation Infrared Spectroscopic and Theoretical Study of Group IV Metal Oxide Clusters: M2O2
Matrix Isolation Infrared Spectroscopic and Theoretical Study of Noble Gas Coordinated Rhodium-Dioxy
Ionization and dissociation of CH3I in intense laser field.
Matrix isolation infrared spectroscopic and theoretical study of noble gas coordinated dipalladium-d
Matrix Isolation Infrared Spectroscopic and Theoretical Study of Dinuclear Chromium Oxide Clusters:
Formation and Characterization of the Oxygen-Rich Hafnium Dioxygen Complexes: OHf(2-O2)(2-O3), Hf(2-
Reactions of Late Lanthanide Metal Atoms with Water Molecules: A Matrix Isolation Infrared Spectrosc
Formation and Characterization of the Tetranuclear Scandium Nitride:Sc4N4.
Interconvertible Side-On- and End-On-Bonded Oxo-Superoxo Titanium Ozonide Complexes.
Electrospray/VUV Single-Photon Ionization Mass Spectrometry for the Analysis of Organic Compounds.
Theoretical and REMPI spectroscopic study on phenylhydrazine and phenylhydrazine-(Ar)n (n=1, 2) van
Pb-m-phenyl (m=1-5) complexes: an anion photoelectron spectroscopy and density functional study.
On the photofragmentation of SF[sub 2][sup +]: Experimental evidence for a predissociation channel.
Observation of the 5p Rydberg states of sulfur difluoride radical by resonance-enhanced multiphoton
Matrix Infrared Spectra and Density Functional Calculations of TiO3 and TiO5 in Solid Argon.
Photoelectron Spectroscopic and Theoretical Study of Aromatics - - Pbm Anionic Complexes (Aromatics
Formation and Characterization of Two FeO3 Isomers in Solid Argon.
CO Activation on the Late Lanthanide Dimers: Matrix Infrared Spectra of the Ln2[2-C, O)]x (Ln = Tb,
Experimental and theoretical investigation on binary semiconductor clusters of B/Si and Al/Si.
高分辨光解碎片平动能谱研究C2H5I的紫外光解.
Study on the (HI)m(H2O)n Clusters by Photofragment Translational Spectroscopy and Ab-Initio Calculat
Vibrational spectrum of p-fluoroanisole in the first excited state (S1) and ab initio calculations.
Resonance enhanced multiphoton ionization spectroscopy and theoretical calculations of cis and trans
The laser-induced fluorescence study of A2[Sigma]- - X2[Pi]i band system of CuS.
Noble-Gas-Induced Disproportionation Reactions: Facile Superoxo-to-Peroxo Conversion on Chromium Dio
Experimental and Theoretical Studies on the Complexes of [Pbm#Pyridyl] (m = 1#4).
Matrix Isolation Infrared Spectroscopic and Theoretical Study of the Hydrolysis of Boron Dioxide in
Photofragment translational spectroscopy of n-C3H7I and i-C3H7I near 280 and 304 nm.
Probing the intermediates in the MO + CH4 ? M + CH3OH reactions by matrix isolation infrared spectro
Resonance-enhanced photon excitation spectroscopy of the even-parity autoionizing Rydberg states of
Noble Gas-Transition-Metal Complexes: Coordination of VO2 and VO4 by Ar and Xe Atoms in Solid Noble
F^2∑^＋-X^2∑^＋ Band System of Cobalt Carbide
二元合金团簇CoGen^-（n=1—12）的结构和稳定性
溴甲烷在强激光场中的电离和解离
超声射流冷却S2自由基激光诱导荧光激发谱
唐紫超的项目
含锗二元团簇负离子的光电子谱及零动能谱研究
期刊论文 2