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中文摘要：
研制新型高效四氮唑微孔配位聚合物作为气体吸附和荧光探针材料，为气体能源储存和生物、医学领域的分析与检测，提供新的材料、技术和方法具有非常重要的意义。本项目拟采用[2+3]环加成合成方法，进行新型四氮唑微孔配位聚合物的设计、合成及性能方面的研究，发掘该类具有独特结构材料的优异物理和化学性质。通过开展四氮唑配位聚合物的结构调变研究，探索由于组分、结构和作用力变化而引起的气体吸附性能与荧光发光特征变化，获得提高气体吸附和荧光探针性能的新方法，为相关具有优越性能的荧光探针和气体吸附性能的复合功能四氮唑配位聚合物功能材料的开发及应用提供理论依据。
英文摘要：
Tetrazole；Coordination polymers；Fluorescence；In situ；Magnetism
结论摘要：
设计合成不同的四氮唑有机配体作为桥配体前驱体，在水热或溶剂热的条件下，利用 [2 + 3]环加成方法原位合成各种新颖同核或异核结构的过渡金属四氮唑配位聚合物。研究了反应前驱物、温度、第二配体等对四氮唑配位聚合物的空间排列及维数的影响；研究了这些化合物的气体吸附、发光、磁性、非线性光学等方面的性质与功能。探讨空间结构与性质和性能之间的关系规律，建立了四氮唑配体与过渡金属离子自组装成结构新颖的同核或异核四氮唑配位聚合物的新方法，为这些四氮唑配位聚合物结构与功能模拟的进一步研究提供新的理论与实验基础。在国际著名学术杂志发表论文二十篇。
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期刊论文
Self-Assembly of 1D, 2D, and 3D Lanthanide-Metal Coordination Polymers Based on a 2-(Pyridin-4-yl)-4
Secondary Branching and Nitrogen Doping of ZnO Nanotetrapods: Building a Highly Active Network for P
3d-4f Heterometallic coordination polymers constructed by tetranuclear lanthanide-based cluster as s
Syntheses, structure, and properties of a series of three-dimensional lanthanide-based hybrid framew
Hollow CuFe(2)O(4) spheres encapsulated in carbon shells as an anode material for rechargeable lithi
A series of three-dimensional 3d-4f cyanide heterometallic coordination polymers: synthesis, crystal
A series of three-dimensional 3d–4f cyanide heterometallic coordination polymers: synthesis, crystal
A series of unusual three-dimensional 3d–4f (Ln/Cu/Cl/Br) cyanide heterometallic coordination polyme
Hydrothermal syntheses and crystal structures of a series of 3d–4f heterometallic tetrazole-based co
A series of unusual three-dimensional 3d-4f (Ln/Cu/Cl/Br) cyanide heterometallic coordination polyme
Construction of diverse Cd-II/Zn-II coordination polymers based on 5-(quinolyl)tetrazolate generated
A Novel Zinc(II)-Organic Coordination Framework Involving in situ Tetrazole Ligand Synthesis: Crysta
Novel tetrazole-based metal–organic frameworks constructed from in situ synthesize bifunctional liga
A New Family of 3d？4f Heterometallic Tetrazole-based Coordination Frameworks: In Situ Tetrazole Liga
Novel tetrazole-based metal-organic frameworks constructed from in situ synthesize bifunctional liga
Hydrothermal syntheses, crystal structures and properties of three new zinc(II) coordination polymer
Construction of three new coordination polymers based on 5-ethyltetrazole (ET) generated via in situ
Syntheses, structures and photoluminescence of Cd(II) coordination polymers based on in situ synthes
In situ hydrothermal syntheses of five new cadmium(II) coordination polymers based on 3-(1H-tetrazol
In situ hydrothermal synthesis of dysprosium(III) single-molecule magnet with lanthanide salt as cat
((1H-tetrazol-5-yl) methyl) pyridine-based metal coordination complexes: in situ tetrazole synthesis
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