欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
位置：立项数据库 > 立项详情页
中文摘要：
设计合成一系列以苯并咪唑及其衍生物为配位端基的"间隔基团-(配位端基)n"型有机配体分子，通过改变配位端基间间隔基团的长度、大小、刚柔性，以及配位端基的个数（n = 2-6）、亲疏水性和极性，调节配体的配位特性和功能性，进一步与过渡金属离子和简单金属化合物单元组装零维到多维超分子配位聚集体，达到控制、调节配位超分子拓扑结构和物化性质的目的。着重依据超分子手性概念，从配位聚合物的手性设计出发，选择合成一些具有构型手性的非心对称性线性、风扇型三脚架和多臂式配体，利用金属中心多面体的内在手性或立体构象结合配体手性或者辅助手性因素创造非对映异构体的方法，设计并构筑手性配位超分子聚集体。进一步研究结构多样性与组装基元的内在联系及组装过程的溶液动力学，并研究相应超分子化合物的谱学与光、电、磁等物理化学性能，尝试配位聚集体在不对称催化、医药和生物活性等方面的应用。
结论摘要：
英文主题词Supramolecular chirality, supramolecular coordination assemblies, benzimidazole, self-assembly, physical-chemical property
成果综合统计
期刊论文
会议论文
专利
获奖
著作
期刊论文
Structure, biological and electrochemical studies of transition metal complexes from N,S,N ' donor l
Assembly of 1D meso coordination polymer from a chiral mononuclear complex by N-deprotonation of the
Assembly of CdI2-type coordination networks from triangular ligand and octahedral metal center: topo
Guest-inclusion behavior of double-strand 1D coordination polymers based on N,N '-type Schiff base l
Evolution of Spherical Assemblies to Fibrous Networked Pd(II) Metallogels from a Pyridine-Based Trip
Guest Inclusion and Interpenetration Tuning of Cd(II)/Mn(II) Coordination Grid Networks Assembled fr
Temperature-Dependent Guest-Driven Single-Crystal-to-Single-Crystal Ligand Exchange in a Two-Fold In
Solvent-free synthesis of a Pd(II) coordination networked complex as reusable catalyst based on 3,5-
Structural and photoluminescent studies of lanthanide complexes with tripodal triRNTB (N-substituted
Assembly of a 1D Coordination Polymer through in Situ Formation of a New Ligand by Double C-C Coupli
Dehydration and rehydration behavior of a trinodal topological 3-D framework of Cd(II) benzimidazole
Synergistic metal and anion effects on the formation of coordination assemblies from a N,N '-bis(3-p
相关项目
苏成勇的项目