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中文摘要：
本项目开展了由金属卤簇模块构建的杂化微孔材料的设计、合成与性能研究工作。在杂化碘化铜等体系中通过有机胺配体、简单无机反应原料调控，自组织合成了系列具有特殊骨架结构的无机-有机杂化材料单晶，并进行了单晶结构分析，确定结构。进行了一定的物性表征和理论计算，考察了新型杂化金属卤簇化合物结构的稳定和生成机制，在一定意义上拓展了分子尺度裁剪研究。
结论摘要：
英文主题词hybrid materials; hydrothermal synthesis; metal-halide clusters; secondary building unit.
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期刊论文
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期刊论文
Solution-mediated syntheses and characterizations of two new zincophosphites [C6H14N2](0.5)[Zn(H2PO3
Synthesis, characterization and magnetic property of a new 3D iron phosphite: [C4N3H14][Fe-3(HPO3)(4
Synthesis and Structure Characterization of (C6H8N3)I-+(3)- and [(Cu3I4) (C8H17N2)] Based on in situ
Syntheses, characterization, and luminescent properties of monoethylzinc complexes with anilido-imin
Synthesis, structures and catalytic properties of stable oxo-bridged half-sandwich titanium complexe
Synthesis and characterization of a new layered fluoroaluminophosphate (C4H11NOH)(3.5)[Al-4(PO4)(5)F
Structural variation from 1D to 3D: Effects of ligands and solvents on the construction of lead(II)-
Hydrothermal synthesis and X-ray crystal structure of four inorganic-organic hybrid compounds in van
Assembly of two 3-D metal-organic frameworks from Cd(II) and 4,5-imidazoledicarboxylic acid or 2-eth
Hydrothermal synthesis and crystal structure of polar and nonpolar compounds in indium iodate family
Synthesis of copper halide coordination polymers with ligands formed by in situ cyclization of 2-ami
2H(3)O-[Co-8(HPO3)(9)(CH3OH)(3)]-2H(2)O: An open-framework cobalt phosphite containing extra-large 1
[Ni(1,2-PDA)(3)](2)(HOCH2CH2CH2NH3)(3)(H3O)(2) [Ge7O14X3](3) (X = F, OH): A new 1D germanate with 12
Syntheses and structures of two chiral zincophosphite compounds: [Zn(C8H8N2)(HPO3)] and (C6H13N2)[Zn
Hydrothermal synthesis and characterization of two novel three-dimensional vanadium phosphites: vert
A germanate built from a 6(8)12(6) cavity cotemplated by an (H2O)(16) cluster and 2-methylpiperazine
Hydrothermal synthesis, structural characterisations, and photoluminescence properties of four inorg
Hydrothermal synthesis and structural characterization of a family of lanthanide tartrates: [Ln(2)(C
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