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中文摘要：
在水热及溶剂热条件下，采用无机、有机及配合物阳离子为结构导向剂，以铝、锗等金属醇盐为原料，通过金属醇盐的水解来调控手性金属中心的形成，进一步探索手性金属中心与手性或非心结构硼-氧簇单元间"协同作用"的条件，进而构建手性或非心结构的金属硼酸盐与硼锗酸盐产物。对获得的手性或非心结构金属硼酸盐及硼锗酸盐化合物的二阶非线性光学性质、铁电性质、热稳定性及离子交换性质等进行研究，筛选具有良好二阶非线性光学、铁电及离子交换等性质的功能材料。系统地总结不同结构导向剂存在情况下，手性金属中心与手性或非心结构硼-氧簇间"协同作用"的条件及规律、导向剂种类与产物结构、产物结构与产物性能间的关系。该项目的实施必将推动功能材料的合成化学、结构化学、固体化学、材料科学及分子筛化学等学科领域的发展，同时为寻找新型的功能材料打下基础，不仅具有十分重要的科学意义，而且具有潜在的应用前景。
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期刊论文
Hydrothermal Synthesis and Crystal Structure of a Novel Sandwich Germanotungstate: [Ni(dien) (H2O)3]
Two Novel 1-D Organic-Inorganic Composite Phosphotungstates Cons- tructed from [Ln(α-PW11O39)2]11- U
A series of 3d-4f heterometallic frameworks comprising 2D lanthanide-organic layers and diverse Cu-c
A new 3-D Gd-Cu heterometallic poly- mer [Gd2Cu3(bpy)2(ip)6]·6H2O with a non-interpenetrated alpha-P
The first polyoxometalate-templated four-fold interpenetrated coordination polymer with new topology
(CH3NH3)2[GeB4O9]: An organically- templated chiral borogermanate with second-order nonlinear and fe
Two New Dawson-Type Polyoxometa- lates: 1D Chain Made by Mono- Dawson Units and 2D Layer Made by Dou
Hydrothermal Synthesis and Structural Characterization of a New Keggin- Type Tungstogermanate Contai
Hydrothermal Synthesis and Crystal Structure of a New 2-D Organic- Inorganic Hybrid Wells-Dawson-Typ
Hydrothermal Synthesis and Structural Characterization of Three One-Dimen- sional Heteropolytungstat
Lanthanide Germanate Cluster Organic Frameworks Constructed from {Ln8Ge12} or {Ln11Ge12} Cage Cluste
Hydrothermal Synthesis and Structure of A Novel Organic-Inorganic Hybrid Polyoxotungstate: H5[Cu(en)
A Series of Vanadogermanates from 1D Chain to 3D Framework Built by Ge-V- O Clusters and Transition-
The first three-fold interpenetrated framework with two different four- connected uniform nets of 66
Combination Chemistry of Hexa- Copper-Substituted Polyoxometalates Driven by the CuII-Polyhedra Dist
Metal-Organogermanate Frameworks Built by Two Kinds of Infinite Ge-O Chains with High Thermostabilit
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