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中文摘要：
以分子筛为代表的无机微孔晶体材料在工业催化、吸附、分离以及高新技术先进材料领域有着极为重要的应用。开发以功能为导向，定向设计与合成具有特殊孔道结构的无机微孔晶体具有重要的理论与实际意义。本项目以具有特殊孔道结构，特别是手性孔道和超大孔道结构的开放骨架无机物为主要研究对象，开展了特殊结构开放骨架无机物的分子设计和可控合成。独创性地开拓了具有特定孔道结构开放骨架结构设计的路线与方法，在国际上率先建立了完善的开放骨架无机物数据库—ZEOBANK，深入总结了特殊结构开放骨架合成－结构规律，在此基础上，成功地开拓出一系列具有特殊结构与功能的开放骨架无机物，它们具有手性孔道、超大孔道以及特殊配位态开放骨架结构，为实现以功能为导向进行无机功能材料的定向合成提供了重要的理论与实验基础。
结论摘要：
英文主题词Inorganic Porous Crystal; Extra-Large Pore; Chiral; Design; Synthesis
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期刊论文
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