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中文摘要：
对固体核磁共振技术及其在分子筛催化剂"活性中心"的结构、吸附分子行为及催化反应机理的应用进行了深入研究。这包括（1）新型磷酸铝分子筛中硅、镁离子的取代机理（2）金属离子在分子筛催化剂上的分布状态及表面修饰作用（3）微孔、分子筛的固体酸性（4）硅铝沸石分子筛中各种铝的状态和"NMR不可观测铝"的起源（5）分子筛催化剂上的催化反应机理。(6) 分子筛催化剂的孔道结构。(7)层状硅酸钠材料的水合行为及钠离子状态
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期刊论文
Relationship between 1H chemical shifts of deuterated pyridium ions and Bronsted acid strength of so
High Activity of Amine-doped H-ZSM-5 Zeolite in the Ethene Protonation Reaction as Revealed by Embed
Solid-State NMR Spectroscopy of Anionic Framework Aluminophosphates: A New Method to Determine the A
Mesoporous MSU Materials Functionalized with Sulfonic Group: A Multinuclear NMR and Theoretical Calc
Super hydrophobic mesoporous silica with anchored methyl groups on the surface by a one-step synthes
Intensively competitive adsorption for heavy metal ions by PAMAM-SBA-15 and EDTA-PAMAM-SBA-15 inorga
Rapid analysis of isotopically unmodified amino acids by high-resolution 14N-edited 1H-13C correlati
Acid Sites and Oxidation Center in Molybdena Supported on Tin Oxide as Studied by Solid-State NMR Sp
Reactivity Enhancement of 2-Propanol Photocatalysis on SO42-/TiO2: Insights From Solid-state NMR Spe
Interactions between Nafion resin and protonated dodecylamine modified montmorillonite: A solid stat
Solvent-free preparation of nanosized sulfated zirconia with Bronsted acidc sites from a simple calc
Comparative study of sol-gel-hydrothermal and sol-gel synthesis of titania-silica composite nanopart
Synthesis and characterization of a new layered fluoroaluminophosphate (C4H11NOH)(3.5) [Al-4(PO4)(5)
Arrangement, Conformation and Mobility of Surfactant Molecules Intercalated in Montmorillonite Prepa
Crystallization of AlPO-5 aluminophosphate molecular sieve prepared in fluoride medium: a multinucle
Unambiguously distinguishing Si[3Si,1Al] and Si[3Si,1OH] stuctural units in zeolite by 1H/29Si/27Al-
Synthesis, crystal structure, and solid-state NMR spectroscopy of a new open-framework aluminophosph
Br?nsted and lewis acidity of the BF3/(-Al2O3 alkylation catalyst as revealed by solid-state NMR spe
Bronsted/Lewis acid synergy in dealuminated HY zeolite: a combined solid-state NMR and theoretical c
The domain structure and mobility of semi-crystalline poly(3-hydroxybutyrate) and poly(3- hydroxy bu
Studies on a new carrier of trimethylsilyl-modified mesoporous material for controlled drug delivery
Amnio acid adsorption on mesoporous materials: influence of types of amino acids, modification of me
13C Shielding Tensors of Crystalline Amino Acids and Peptides:Theoretical Prediction on the Periodic
Formation, Location and Photocatalytic Reactivity of Methoxy Species on Keggin 12-H3PW12O40: A Joint
Combined DFT Theoretical Calculation and Solid-State NMR Studies of Al Substitution and Acid Sites i
Prediction of the 13C NMR chemical shifts of organic species adsorbed on H-ZSM-5 zeolite by the ONIO
Location, Acid Strength, and Mobility of the Acidic Protons in Keggin 12-H3PW12O40: A Combined Solid
Local structure of hydroxy-peroxy apatite: A combined XRD, FT-IR, Raman, SEM, and solid-state NMR st
会议论文
A Combined Solid-State NMR Spectroscopy and Theoretical Calculation Study of Bronsted/Lewis Acid Syn
Acidity of Mesoporous MoOx/ZrO2 and WOx/ZrO2 Materials: A Combined Solid-State NMR and Theoretical C
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