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中文摘要：
配位聚合物以其特定的结构、性能以及潜在的应用而受到人们的广泛关注。本项目在本课题组以前工作的基础上开展了功能配位聚合物晶体工程方面的研究工作，设计合成了含1-咪唑基、4-咪唑基、羧基等配位基团的有机多齿配体，利用配位化学和晶体工程学的原理和方法通过有机多齿配体与锰(II)、铜(II)、银(I)、锌(II)、镉(II)等不同配位构型的过渡金属、稀土金属盐反应构筑了新型配位聚合物，研究其结构以及离子交换、分子识别等性能，探讨了影响配位聚合物结构和性能的因素，为总结配合物结构与性能之间的关系，实现金属配合物结构和性能的可控合成提供基础。本项目已发表标注有该项目资助的SCI论文73篇(其中影响因子大于3.0的论文37篇)，被引频次总计549篇次，去除自引的被引频次总计405篇次。
结论摘要：
英文主题词Crystal engineering; Ion exchange; Molecular recognition; Design and synthesis
成果综合统计
期刊论文
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期刊论文
Synthesis, Structures, and Properties of Zinc(II) and Cadmium(II) Complexes with 1,2,4,5-Tetrakis(im
Synthesis and characterization of metal complexes with a mixed 4-imidazole-containing ligand and a v
Metal-organic frameworks with pyridyl- and carboxylate-containing ligands: syntheses, structures and
Syntheses, structures and properties of silver(I) complexes with flexible 1,3,5-tris(pyridylmethoxyl
Syntheses and characterization of inorganic-organic hybrids with 4-(isonicotinamido)phthalate and so
Imidazolate-bridged dinuclear copper(II) complex with new macrocyclic ligand bearing two 1H-imidazol
Synthesis, Crystal Structure, and Photoluminescence of a Series of Zinc(II) Coordination Polymers wi
Hydrothermal Syntheses, Crystal Structures and Magnetic Property of Two Copper(II) Complexes Constru
Counteranion-directed assembly of zinc(II) coordination polymers with 1,3,5-tris(1-imidazolyl)benzen
Syntheses, crystal structures and properties of three novel coordination polymers with tripodal imid
Synthesis, structure and property of manganese(II) complexes with mixed tetradentate imidazole-conta
Interpenetrating and Self-Penetrating Zinc(II) Complexes with Rigid Tripodal Imidazole-Containing Li
Shape-controlled zinc(II) oxide nanomaterial constructed from three-dimensional zinc(II) coordinatio
Metal-organic frameworks with six- and four-fold interpenetration and their photoluminescence and ad
Synthesis and Characterization of 3d-3d Homo- and Heterometallic Coordination Polymers with Mixed Li
Syntheses and crystal structures of two supramolecular isomers of manganese(II) with 3,5-bis(isonico
Syntheses, structures and properties of novel lanthanide complexes with 5-(1H-imidazol-4-yl)methylam
Imidazolate-bridged dicopper(II) and copper(II)-zinc(II) complexes of macrocyclic ligand with methyl
New metal complexes with 5-(1H-imidazol-4-ylmethyl)aminoisophthalic acid: Syntheses, structures, ele
New metal-organic architectures of cobalt(II), nickel(II) and zinc(II) with tripodal ligand 5-(1H-im
Synthesis and Crystal Structure of 1-Bromo-3,5-bis(imidazol-1-ylmethyl)benzene-Cd(II) Complexes with
Synthesis, structure and fluorescence of novel cadmium(II) and silver(I) complexes with in situ liga
Syntheses, structures and photoluminescent property of coordination complexes with 2-(1H-1,2,4-triaz
Syntheses, structures and properties of novel d10 coordination polymers based on 4-[(1H-imidazol-4-y
Cadmium(II) coordination polymers with flexible tetradentate ligand 1,2,4,5-tetrakis(imidazol-1-ylme
Coordination Polymers with Varied Metal Centers and Flexible Tripodal Ligand 1,3,5-Tris(imidazol-1-y
Synthesis and Crystal Structure of an Unprecedented Supramolecular Cornplex [Co(mu(2)-ClO4)(2)(H2O)(
Three-dimensional fourfold interpenetrated (10, 3)-b nickel(II) framework with 5-(isonicotinamido)is
Hydrothermal Syntheses and Crystal Structures of Two Metal Complexes with Mixed 1,2,4-Benzenetricarb
Syntheses, structures, and properties of lead(II) and nickel(II) complexes with 3,5-di(1H-imidazol-1
Anion- and auxiliary ligand-directed synthesis of cadmium(II) complexes with 3,5-di(1H-imidazol-1-yl
Syntheses, structures and photoluminescence properties of cadmium(II) and zinc(II) complexes with py
A series of silver(I)-lanthanide(III) heterometallic coordination polymers: syntheses, structures an
pH Dependent Structural Diversity of Metal Complexes with 5-(4H-1,2,4-Triazol-4-yl)benzene-1,3-dicar
Porous zinc(II) frameworks with 5-(isonicotinamido)isophthalate: Syntheses, structures and propertie
Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frame
Temperature dependent selective gas sorption of the microporous metal-imidazolate framework Cu(L) H(
Porous cobalt(II)-imidazolate supramolecular isomeric frameworks with selective gas sorption propert
Synthesis, structure and property of lanthanide-organic frameworks with pyridyl- and carboxylate-con
Syntheses and Structures of Silver(I) Complexes with New Tripodal Ligand Containing Propanenitrile a
Large (H2O)(56)(OH)(6) and (H2O)(20) clusters inside a nanometer-sized M6L8 cage constructed by five
Silver(I) complexes with oxazoline-containing tripodal ligands: Structure variation via counter anio
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