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中文摘要：
手性有机催化反应是现代不对称合成化学领域的新研究热点和前沿课题。本项目研究离子型手性有机小分子/聚乙二醇复合体系的形成及其催化反应性能，即设计合成同时具有吡咯烷结构和有机离子片段的系列新型离子型手性胺，探索建立离子型手性胺与聚乙二醇相互识别形成"手性开环聚醚"复合催化体系的有效途径和方法及其形成机制，以不对称催化碳-碳键和碳-杂原子键的形成为反应模型，系统研究离子型手性胺及其复合催化体系对底物的适应性，探索手性胺结构与催化性能的关系以及"手性开环聚醚"体系的催化作用机制。这些研究工作的实施将为进一步深入理解手性有机小分子催化作用规律和微反应环境对催化性能的影响机制建立必要的知识积累，为新型手性有机小分子催化剂及其催化体系和催化方法的设计研究提供借鉴和指导。
结论摘要：
英文主题词Small chiral organic molecules; Chiral amines; Poly(ethylene glycol)s; Asymmetric catalysis.
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期刊论文
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