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中文摘要：
以分子基光电功能材料研究为导向，以内光电效应中的光电导和光生伏特效应为研究内容，利用分子设计和能带工程的基本原理，合成多个系列具有金属配位点的线性有机芳杂环半导体分子及其不同种类、价态、氧化还原特性和抗衡离子的配位化合物，通过调控其能级结构使之用于柔性光敏与光伏薄膜与器件的研究。线性芳杂环半导体分子一般含有两种以上具有多种取代基的1,10-邻菲咯啉、噻吩、咪唑、吡啶、吡咯、噻唑、氮唑、嘧啶等芳杂环，其合成是通过组合C－C和C－N键的交叉偶联和配位键的拓展实现。此类分子中含有多种含氮配体，可通过选择合成不同的有机芳杂环扩展体系和不同的配合物来调控所得半导体化合物的HOMO和LUMO轨道能级以及电子吸收光谱和发光特性等。选择这些结构新颖的半导体化合物，一方面制成结构和性能可调的纳米复合薄膜与器件用于研究其光敏甚至光开关特性；另一方面制成能级匹配的宽光谱吸收的染料分子用于柔性硅基光伏电池的研究。
英文摘要：
Optoelectronic functional material；band gad engineering；aromatic heterocyclic semiconductor；photoresponsive film and device；photovoltaic device
结论摘要：
本项目以分子基光电功能材料研究为导向，以内光电效应中的光电导和光生伏特效应为研究内容，利用分子设计和能带工程的基本原理，合成了多个系列具有金属配位点的线性有机芳杂环半导体分子及其不同种类、价态、氧化还原特性和抗衡离子的配位化合物，通过调控其能级结构使之用于柔性光敏与光伏薄膜与器件的研究。通过4年多的研究，我们已经完成了圆满完成了任务书预期的目标，2012年以来申请人以责任作者一共发表带有国家自然科学基金标注的SCI论文62篇，其中影响因子大于3.0的文章36篇。此外，我们还成功申请5项国家发明专利（申请人为第一完成人，南京大学为第一完成单位），在此期间还有6项国家发明专利获得授权。
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期刊论文
Three copper(II) complexes of 4-formylbenzoate obtained from the degradation of Schiff-base C=N doub
Synthesis, Crystal Structures, Cis-Trans Conformation and Substituent Effects of Manganese(II) and C
Visualizedacid-base discoloration and optoelectronic investigations for azines andazomethines having
Sodium templated formation of a unique tetradecanuclear {Zn-12(mu(3)-OH)(6)Na-2(mu(2)-O)}(18+) heter
Structural and Spectral Studies of Cis Cadmium(II), Manganese(II) and Nickel(II) Complexes Having 2-
Construction of identical [2+2] Schiff-basemacrocyclic ligands by LnIII and ZnII template ionsinclud
Variationof cis/trans configuration of3,8-dithiophen and 3,8-di-3-methylthiophen-substituted 1,10-ph
Structuresand photophysical properties of a family of [Ru(dcmb)2]2+ based complexeshaving pyridyl an
Asymmetricimidazole/pyrene/pyrazine based D-p-A compounds showing visualized acidichromismand near-i
Afamily of extended heterocyclic oligomers with thienylene/thiazolylene vinylenecores and triphenyla
Luminescentlanthanide(III)-cored complexes based on the combination of 2-(5-bromothiophen)imidazo[4,
Structure-performance relationship for afamily of disperse azo dyes having the same D–π–A 4-nitro-4&
cis and trans Isomers distinguished byimidazole N-alkylation afterDebus-Radziszewski reaction starti
Construction of Pendant-Armed Schiff-Base Macrocyclic Dinuclear Zinc Complexes and Their Selective R
Architectural Diversity for Anion-Mediated Self-Assembly of Four Pairs of Silver(I) Polymeric Isomer
Architectural alterations from 1D to 3D coordination polymers based on a pair of isomeric linear and
Syntheses and Crystal Structures of Two Manganese(II) Coordination Polymers Having 3,4-Diimidazol-Th
Base-induced self-assembly for one-dimensional coordination polymers via chiral pendant-armed Schiff
Advantage of N-alkylation Strategy in Keeping the Molecular Planarity for Oligothiophene/Imidazole/1
The first observation of cis and trans isomers for bibenzo[d]imidazole-based compounds influenced by
Zinc halide template effects on the construction of [1+1] flexible Schiff-base macrocyclic complexes
9. Distinguishable Zn(II) and Pb(II) template effects on forming pendant-armed Schiff-base macrocycl
Distinguishable photovoltaic performance on dye-sensitized solar cells by using ruthenium sensitizer
Symmetrical fluorescent oligothiophene and benzene centered bispyrenoimidazole derivatives with doub
Variations of structures and solid-state conductivity of isomeric silver(I) coordination polymers ha
A ruthenium(II) complex having a ligand undergoing partial C=N cleavage and unusual double-bond shif
Synthesis,structure, photophysical and electrochemical properties of series of new fac-triscyclometa
Tuning the Spectroscopic, Electrochemical and Single-Crystal Conductance Properties of a Series of R
Asymmetrical/Symmetrical D？π？A/D？π？D Thiazole-Containing Aromatic Heterocyclic Fluorescent Compounds
Influence of the pendant arm, halide and solvent on high-efficient-tuning [1+1] and [2+2] Schiff-bas
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