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Copper（I）-Catalyzed Trifluoromethylation of Phthalic Anhydride Derivatives with （Trifluoromethyl）trimethylsilane
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 分类：TQ424.1[化学工程] O626[理学—有机化学;理学—化学]
  • 作者机构：[1]Shanghai Key Laboratory of Chemical Biology, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China, [2]Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
  • 相关基金：Acknowledgement We are grateful for financial supports from the National Natural Science Foundation of China （Nos. 21072057, 21272070）, the 973 Program （No. 2010CB126101）, the Key Project in the National Science ＆ Technology Pillar Program of China in the twelfth five-year plan period （No. 2011BAE06B05）.
作者： Mingxi Wu[1], Mingjin Wang[1], Song Cao[1,2]
关键词： 三氟甲基, 三甲基硅烷, 铜(I), 生物催化, 反应混合物, 苯酐, 邻苯二甲酸酐, 甲基化试剂, trifluoromethylation, copper（l）-catalyzed, phthalic anhydrides, （trifluoromethyl）trimethylsilane
中文摘要：

使用的代替的酞酸酐(trifluoromethyl ) 的有效催化铜的 trifluoromethylation trimethylsilane (Me3SiCF3 ) 作为亲核的 trifluoromethylating 试剂面对 1,10-phenanthroline 和 KF，由与水熄灭反应混合列在后面被开发了。可能的机制被建议。

英文摘要：

An efficient copper-catalyzed trifluoromethylation of substituted phthalic anhydrides using （trifluoromethyl） trimethylsilane （Me3SiCF3） as a nucleophilic trifluoromethylating reagent in the presence of 1,10-phenanthroline and KF, followed by quenching the reaction mixture with water has been developed. A possible mechanism was suggested.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175