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Near-infrared spectroscopy-based quantification of substrate and aqueous products in wastewater anaerobic fermentation processes
  • ISSN号:0253-2468
  • 期刊名称:《环境科学学报》
  • 时间:0
  • 分类:O657.33[理学—分析化学;理学—化学] S216.4[农业科学—农业机械化工程;农业科学—农业工程]
  • 作者机构:[1]Department of Chemistry, University of Science and Technology of China, Hefei 230026, China
  • 相关基金:Supported by the National Natural Science Foundatoin of China-Japan Science & Technology Agency Joint Project (Grant No. 20610002), National Natural Science Foundatoin of China (Grant No. 50878203), CAS (Grant No. KSCX2-YW-G-001), and National Basic Research Program of China (Grant No.2004CB719602)
中文摘要:

在这研究, Fourier 变换在红外线附近(FT-NIR ) 技术被用于过程监视厌氧的发酵。直角的信号修正(振荡) 方法被用作 NIR 光谱预处理选择。刻度模型被建立,方法的确认与蔗糖,乙醇和内容决定了由的不稳定的丰满的酸(VFA ) 被执行一个王位和煤气的层析方法分别地。光谱范围和内部潜伏的变量的数字为最好的关联系数被优化。蔗糖的测试集合确认导致了预言性能和决心的关联系数的优秀测量是 0.930。为单个 VFA 和全部的 VFA 内容的类似的预言统计被获得。这些结果证明 NIR 光谱学技术能确定在废水的不稳定的丰满的酸和蔗糖的内容厌氧的发酵过程。

英文摘要:

In this study, a Fourier transform near-infrared (FT-NIR) technique was used for process monitoring of anaerobic fermentation. Orthogonal signal correction (OSC) method was used as NIR spectral pre- processing options. Calibration models were established and the validation of the method was per- formed with the sucrose, ethanol and volatile fatty acids (VFAs) contents determined by the anthrone and gas chromatography methods, respectively. Spectral range and the number of internal latent variables were optimized for the best correlation coefficient. Test set validation of sucrose resulted in excellent measurement of prediction performance and the correlation coefficient of determination is 0.930. Similar prediction statistics for individual VFA and total VFA contents were obtained. These re- sults proved that the NIR spectroscopy technology is able to quantify the contents of both volatile fatty acids and sucrose in wastewater anaerobic fermentation process.

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期刊信息
  • 《环境科学学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:汤鸿霄
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjkxxb@rcees.ac.cn
  • 电话:010-62941073
  • 国际标准刊号:ISSN:0253-2468
  • 国内统一刊号:ISSN:11-1843/X
  • 邮发代号:82-625
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰地学数据库,荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:56074