中文摘要：

本文对在超临界二氧化碳（ScCO2）中进行的聚合反应进行了综述。评述了ScCO2作为聚合反应介质的优点,以及在ScCO2中可进行的聚合反应类型,包括均相聚合、沉淀聚合、分散聚合、乳液及反相乳液聚合、阳离子聚合、开环聚合、熔融态缩聚、溶胶-凝胶聚合、聚合物混合合成、链催化转移聚合、氧化-偶合反应聚合、氮氧自由基可控活性聚合、原子转移自由基聚合、可逆加成-断裂链转移、电化学聚合、原子转移聚合与酶催化开环聚合两种活性聚合在ScCO2中同时聚合、二氧化碳作为原料共聚合等。

英文摘要：

The recent progress of polymerization in supercritical carbon dioxide is reviewed. The advantage of supercritical carbon dioxide used as an environmental medium in polymerization and reactions in supereritical carbon dioxide are described. It includes homogeneous free radical polymerizations, precipitation free radical polymerizations, dispersion free radical polymerizations, emulsion and inverse emulsion free radical polymerizations, cationic polymerizations, ring-opening polymerization, melt-phase condensation polymerizations, sol-gel polymerizations, polymer blend synthesis, catalytic chain transfer polymerizations, oxidative coupling polymerization, nitroxide-mediated radical dispersion, atom-transfer radical polymerization, reversible addition-fragmentation chain transfer polymerization, electrochemical polymerization, copolymerization of carbon dioxide simultaneous one-pot combination of enzymatic and chemical polymerization, used as monomer.