试验研究了厌氧—缺氧—好氧(A2O)活性污泥工艺对雌二醇(E2)和乙炔雌二醇(EE2)的去除性能.基于同时去除雌激素和脱氮除磷的考虑,对A2O工艺的部分运行参数如水力停留时间、污泥龄和混合液回流比进行优化.试验结果表明,A2O工艺对污水中雌激素有较强的去除能力.在温度为20℃、污泥回流比为100%的情况下,除磷脱氮和去除雌激素最佳的工艺运行参数为:水力停留时间8h,污泥龄20d,混合液回流比300%.此时,总氮,PO43--P,COD的去除率分别达到81%,95%,84%;E2降到检测限以下,厌氧、缺氧、好氧池各段对E2的去除量分别占总去除量的72%,6%,22%;EE2的去除率大于80%,厌氧、缺氧、好氧各反应池对EE2的去除量分别占总去除量的45%,21%,34%.
Lab-scale experiments were conducted to investigate the degradation potential of 1713-estmdiol (E2) and 17e-ethinyl-estradiol (EE2) by anaerobic-anoxic-oxic (A2 O) activated sludge process. Based on the removal of nutrients and estrogen, the operational parameters such as hydraulic retention time (HRT), sludge retention time (SRT) and the recycle ratio of mixed liquor (r) were optimized. The results indicate that estrogens are dramatically removed by the A2O process. At the fixed temperature of 20℃ and sludge recycle ratio of I00%, the optimum operational parameters for HRT, SRT and r are 8 h,20 d and 300%, respectively. Under the above optimum conditions, the removal efficiencies of TN, P~- - P and COD are 82%, 95% and 84%, respectively. E2 in the final effluent is below the detection limit; of the totallyremoved E2, 72%, 6% and 22% are removed in the anaerobic, anoxic and oxic tanks, respectively. EE2 removal efficiency is more than 80%; the anaerobic, anoxic and aerobic tanks contribute 45%, 21% and 34% of the totally removed EE2, respectively.