基于炉渣离子-分子共存理论(IMCT)建立了CaO-MgO-FeO-Fe2O3-SiO2渣系的磷分配比预报模型,即IMCT-LP模型.比较了该渣系在1823-1873 K时实测的磷分配比、IMCT-LP模型预报的磷分配比及其他6种磷分配比模型的计算结果.与实测值和其他磷分配比模型预报结果相比,由IMCT-LP模型预报的CaO-MgO-FeO-Fe2O3-SiO2渣系的磷分配比更精确.本文建立的IMCT-LP模型不仅可计算该渣系的磷分配比,而且可计算该渣系中碱性离子对(Ca^2++O^2-)、(Mg^2++O^2-)和(Fe^2++O^2-)各自的磷分配比.
A thermodynamic model of the phosphorus distribution ratio( LP) of CaO-MgO-FeO-Fe2O3-SiO2 steelmaking slags was developed based on the ion and molecule coexistence theory( IMCT) of slags and verified by experimental data. The predicted phosphorus distribution ratio of CaO-MgO-FeO-Fe2O3-SiO2 steelmaking slags in a temperature range of 1823 to 1873 K by the developed IMCT-LPmodel is more accurate than the measured as well as the predicted phosphorus distribution by other phosphorus distribution models. The developed IMCT-LPmodel can calculate not only the total phosphorus distribution of the slags but also the respective phosphorus distribution of ion pairs( Ca^2 ++ O^2-),( Mg^2 ++ O^2-),and( Fe^2 ++ O^2-) in the slags.