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Phosphate enrichment mechanism in CaO-SiO2-FeO-Fe203-P205 steelmaking slags with lower binary basicity
  • ISSN号:0454-5648
  • 期刊名称:《硅酸盐学报》
  • 时间:0
  • 分类:TQ153.2[化学工程—电化学工业] TF748.41[冶金工程—钢铁冶金]
  • 作者机构:Beijing Key Laboratory of Green Recycling and Extraction of Metals, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
  • 相关基金:Acknowledgements The work was financially supported by the National Basic Research Priorities Program of China (Nos. 2014CB643401 and 2013AA032003) and the National Natural Science Foundation of China (No. 51372019).
中文摘要:

一个新奇热水的过程被开发从纯锌铁酸盐提取锌(ZnFe 2 O 4) nanopowder 和包含锌的电的弧炉子(EAF ) 清扫使用 hexahydrated 铁的氯化物(FeCl 3

英文摘要:

A novel hydrothermal process was developed to extract zinc from pure zinc ferrite(ZnFe2O4) nanopowder and zinc-containing electric arc furnace(EAF) dust using hexahydrated ferric chloride(FeCl3-6H2O) as a decomposing agent.The effects of solid FeCl3-6H2O to ZnFe2O4 ratio by mass(RF/Z),hydrothermal reaction temperature,and time on zinc extraction were systematically investigated.In the results,when the hydrothermal reaction is conducted at 150℃ for 2 h with RF/Z of 15:20,the efficiency of zinc extraction from ZnFe2O4 reaches97.2%,and the concentration of ferric ions(Fe^3+) in the leaching solution is nearly zero,indicating a high selectivity for zinc.In addition,the zinc extraction efficiency from the EAF dust reaches 94.5%in the case of the hydrothermal reaction performed at 200℃ for 10 h with the solid FeCl3-6H2O to EAF dust ratio by mass(RF/EAF dust) of 15:10.Zinc and iron separation is achieved by adjusting the pH value of the leaching solution according to the different precipitation pH values of metal hydroxides.

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期刊信息
  • 《硅酸盐学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国硅酸盐学会
  • 主编:南策文
  • 地址:北京海淀区三里河路11号
  • 邮编:100831
  • 邮箱:jccsoc@sina.com
  • 电话:010-57811253 57811254
  • 国际标准刊号:ISSN:0454-5648
  • 国内统一刊号:ISSN:11-2310/TQ
  • 邮发代号:2-695
  • 获奖情况:
  • EI Compendex、CA、SA、PI收录期刊,全国核心期刊,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27713