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溶剂效应对金属有机骨架化合物结构的影响
  • ISSN号：0251-0790
  • 期刊名称：《高等学校化学学报》
  • 时间：0
  • 分类：O614[理学—无机化学;理学—化学]
  • 作者机构：[1]吉林大学无机合成与制备化学国家重点实验室,长春130012
  • 相关基金：国家自然科学基金（批准号：20831002 20625102 20571030）资助
作者： 赵环宇[1], 金钊[1], 孙福兴[1], 朱广山[1]
关键词： 溶剂效应, 金属有机骨架化合物, 4, 4'-二苯醚二甲酸, Solvent effect, Metal-organic framework, 4, 4′-Oxybis（benzoic acid）
中文摘要：

以水和DMF为溶剂,在水热（溶剂热）条件下以＂柱撑＂方式利用相同的金属和配体合成了2个不同的新型金属有机骨架化合物[Cd（OBA）（bipy）].DMF（1）和Cd（OBA）（bipy）（2）[OBA=4,4＇-Oxybis（ben-zoic acid）,bipy=4,4＇-bipyridine].单晶X射线衍射分析数据表明,化合物1为二维结构,化合物2为三维结构,两种化合物均为单斜晶系,属于C2/c空间群.

英文摘要：

Two novel compounds Cd（OBA）（bipy） DMF（1） and Cd（OBA）（bipy）（2）（OBA=4,4′-oxybis（benzoic acid）,bipy=4,4′-bipyridine） were synthesized under hydrothermal（solvothermal） condition using DMF and water as solvent,respectively.X-ray diffraction analyses reveal that both the compounds are in the monoclinic and C2/c space group.Compound 1 exhibits a two-dimension framework and compound 2 is a three-dimension framework.

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊（2011版）
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编：周其凤
  • 地址：吉林大学南胡校区
  • 邮编：130012
  • 邮箱：cjcu@jlu.edu.cn
  • 电话：0431-88499216
  • 国际标准刊号：ISSN：0251-0790
  • 国内统一刊号：ISSN：22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:50676