位置：成果数据库 > 期刊 > 期刊详情页
孔径可控的介孔TiO2纳米球的溶剂热合成
  • ISSN号：0251-0790
  • 期刊名称：《高等学校化学学报》
  • 时间：0
  • 分类：O611.4[理学—无机化学;理学—化学] O614.4[理学—无机化学;理学—化学]
  • 作者机构：[1]吉林大学无机合成与制备化学国家重点实验室,长春130012
  • 相关基金：国家自然科学基金（批准号：20831002 20625102 20571030）资助
作者： 黄彩霞[1], 郭明义[1], 张凤[1], 孙福兴[1], 朱广山[1]
关键词： 无模板法, 溶剂热合成, 前驱体, 介孔TIO2, Template-free method, Solvothermal synthesis, Precursor, Mesoporous TiO2
中文摘要：

以具有微孔结构的乙二醇钛（TG）为前驱体,采用无模板法制备了一系列单分散的介孔TiO2纳米球.通过溶剂热处理,微孔前驱体TG原位水解直接转化为具有介孔结构的TiO2纳米球.通过X射线粉末衍射（XRD）、扫描电子显微镜（SEM）、透射电子显微镜（TEM）、傅里叶变换红外光谱（FTIR）及氮气吸附-脱附等对产物进行了表征.测试结果表明,产物具有高结晶性、均一的形貌、可调的孔径和比表面积.

英文摘要：

We report a facile template-free method to fabricate monodisperse mesoporous TiO2 spheres using microporous titanium glycolates（TG） as precursor.By solvothermal treatment,microporous TG can be directly converted into mesoporous TiO2 spheres via in-situ hydrolysis.The products were characterized by XRD,SEM,TEM,FTIR and nitrogen absorption.The results show that the products exhibit high crystallinity,uniform morphology and tunable pore size.These integrated features would make the as-obtained mesoporous TiO2 materials have attractive applications in areas of environmental purification,energy conversion and storage.

同期刊论文项目
高机械强度大面积有序分子筛膜的制备与性质研究
期刊论文 10 会议论文 1
无机化学
期刊论文 59
无机微孔晶体的设计合成与储能性能研究
期刊论文 79
同项目期刊论文
Epitaxial growth of highly-oriented AlPO4-5 molecular sieve films for microlaser systems
Stainless-Steel-Net-Supported Zeolite NaA Membrane with High Permeance and High Permselectivity of O
Zeolite P/NaX composite membrane for gas separation
Preparation of an ordered zeolite MFI film by epitaxial growth
Hierarchical Growth of Large-Scale Ordered Zeolite Silicalite-1 Membranes with High Permeability and
金属有机骨架复合材料RhB／MOF-5的制备及其发光性质
溶剂效应对金属有机骨架化合物结构的影响
Synthesis, structure, and luminescent and magnetic properties of novel lanthanide metal-organic fram
Synthesis, structure and luminescent property of a new 3D porous metal-organic framework with rutile
Mesoporous metal-organic framework with rare etb topology for hydrogen storage and dye assembly
A novel metal-organic framework with the diamondoid topology constructed from pentanuclear zinc-carb
A novel 3D metal-organic framework with the pcu topology constructed from 1,4-diaza-bicyclo[2.2.2]oc
Hydrothermal synthesis and crystal structure of [In-2(HPO3)(4)] center dot(NH3CH2CH2NH3)
Hydrothermal synthesis and structure characterization of a piperazine-templated two-dimenisional cer
Ethyl (E)-3-(2,3-dihydro-1-benzofuran-5-yl)prop-2-enoate
Hydrothermal synthesis and characterization of a new indium phosphite [In-4(HPO3)(7)(H2O)(3)] (NH3CH
3D metal-organic frameworks incorporating water-soluble tetra-p-sulfonatocalix[4]arene
Preparation of Mesoporous Silica Nanoribbons and Nanoflakes with Short Pore Channels Using a Chiral
Synthesis and structure of a new scorpionate-dithio carboxyl oxovanadium complex and an organic dith
Ammonia Borane Confined by a Metal-Organic Framework for Chemical Hydrogen Storage: Enhancing Kineti
A spontaneously resoluted zinc-organic framework with nonlinear optical and ferroelectric properties
A series of 3-D lanthanide coordination polymers constructed from dinuclear building blocks: Synthes
A novel microporous MOF with the capability of selective adsorption of xylenes
High-Capacity Hydrogen Storage in Porous Aromatic Frameworks with Diamond-like Structure
Bio-templated synthesis of highly ordered macro-mesoporous silica material for sustained drug delive
A Family of Highly Stable Lanthanide Metal-Organic Frameworks: Structural Evolution and Catalytic Ac
Targeted synthesis of a 3D porous aromatic framework for selective sorption of benzene
Artificial frustule prepared through a single-templating approach
Selective gas adsorption within a five-connected porous metal-organic framework
High-yield synthesis of MCM-48 at low temperature
Ionothermal Synthesis of Metal-organic Frameworks
Synthesis of zeolite silicalite-1 with chain-like morphology
Synthesis of Novel 3D Lanthanide Oxide Nitrate Compounds with the Zeolite SOD Topology
A rare 3D lanthanide metal-organic framework with the rutile topology: Synthesis, structure and prop
Molecular engineering for synthesizing novel structures of metal-organic frameworks with multifuncti
Synthesis of a SAPO - 34 membrane on macroporous supports for high permeance separation of a CO2 / C
Polymer-Mesoporous Silica Materials Templated with an Oppositely Charged Surfactant/Polymer System f
Synthesis, Structure and Molecular Configuration of a Series of Ionic Salt Compounds of Pyrophosphat
Synthesis and characterization of (h 0l ) oriented high-silica zeolite beta membrane
Synthesis of a metal-organic framework film by direct conversion technique for VOCs sensing
Synthesis and characterization of a novel three-dimensional open-framework: Metal diphosphonate, Zn[
A Series of Three-Dimensional Lanthanide Coordination Compounds with the Rutile Topology
Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface
Synthesis and characterization of pure-silica-zeolite Beta low-k thin films
Poly[diaqua(mu(3)-8-oxidoquinoline-5-sulfonato-kappa N-4,O-8:O-5:O-8)nickel(II)]
Effective heavy metal removal through porous stainless-steel-net supported low siliceous zeolite ZSM
New Prototype Isoreticular Metal-Organic Framework Zn4O(FMA)(3) for Gas Storage
Novel mesoporous silica spheres with ultra-large pore sizes and their application in protein separat
Six Three-Dimensional Metal-Organic Frameworks with (3,4)-, (4,5)-, and (3,4,5)-Connected Nets Based
"Twin Copper Source" Growth of Metal-Organic Framework Membrane: Cu-3(BTC)(2) with High Permeability
Synthesis, crystal structure and properties of inorganic-organic hybrid polymers based on 8-hydroxyl
Preparation and Fluorescence Property of Metal-organic Framework Composite RhB/MOF-5
In situ synthesis of dye-doped stainless-steel-net-supported mesostructured silica film for solid-st
Synthesis, surface and crystal structure investigation of the large zeolite beta crystal
A new two-dimensional Cd-II coordination polymer constructed by pyrazine-2,3-dicarboxylate
溶剂效应对金属有机骨架化合物结构的影响
Solvent Effect for the Synthesis of Metal-organic Framework
Synthesis of porous aromatic framework with tuning porosity via ionothermal reaction
Novel lithium-loaded porous aromatic framework for efficient CO2 and H2 uptake
以芘-炔为基块的共价有机骨架材料的设计合成与表征
Targeted Synthesis of a 3D Crystalline Porous Aromatic Framework with Luminescence Quenching Ability
Ethanol Recovery from Water Using Silicalite-1 Membrane: An Operando Infrared Spectroscopic Study
Challenging fabrication of hollow ceramic fiber supported Cu-3(BTC)(2) membrane for hydrogen separat
Sensitive detection of hazardous explosives via highly fluorescent crystalline porous aromatic frame
Solvothermal Synthesis of Mesoporous TiO2 Spheres with Controllable Pore Size
The synthesis, structure and photoluminescence property of a novel 3D supramolecular compound based
Targeted synthesis of a 2D ordered porous organic framework for drug release
Acid degradable ZnO quantum dots as a platform for targeted delivery of an anticancer drug
Targeted synthesis of a porous aromatic framework with a high adsorption capacity for organic molecu
Synthesis, Structure and Gas Adsorption Property of a Novel 2D Layer Nickel Organo-diphosphonate Com
Elaborate Architecture of the Hierarchical Hen's Eggshell
pH-Triggered Controlled Drug Release from Mesoporous Silica Nanoparticles via Intracelluar Dissoluti
Preparation and Characterization of X-type Zeolite Membrane Supported by Stainless Steel Net
Synthesis of a porous aromatic framework for adsorbing organic pollutants application
A novel low density metal-organic framework with pcu topology by dendritic ligand
Facile fabrication of metal-organic framework films promoted by colloidal seeds on various substrate
Detection of Harmful Gases by Copper-Containing Metal-Organic Framework Films
Growth of preferential orientation of MIL-53(Al) film as nano-assembler
Solvent influence on isomer separation and conformation control of the cyclohexanedicarboxylate liga
Targeted synthesis of micro–mesoporous hybrid material derived from octaphenylsilsesquioxane b
From metal–organic framework (MOF) to MOF–polymer composite membrane: enhancement of low
Co-3(HCOO)(6) Microporous Metal-Organic Framework Membrane for Separation of CO2/CH4 Mixtures
Hydrogen Selective NH2-MIL-53(Al) MOF Membranes with High Permeability
a Multifunctional Nanovehicle for Anticancer Drug Delivery
Microwave-assisted crystallization inclusion of spiropyran molecules in indium trimesate films with
Facile synthesis of ZIF-8 nanocrystals in eutectic mixture
Green removal of aromatic organic pollutants from aqueous solutions with a zeolite-hemp composite
Highly porous and robust ionic MOFs with nia topology constructed by connecting an octahedral ligand
定向合成带电荷多孔芳香骨架材料用于碘单质的捕获和释放
定向合成高效捕获CO2的新型多孔芳香材料
新型锗中心多孔芳香材料的设计合成和表征
不锈钢金属网上L型分子筛膜的连续生长及气体渗透性能
不锈钢金属网支撑的X型沸石膜的制备与表征
溶剂效应对金属有机骨架化合物结构的影响
期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊（2011版）
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编：周其凤
  • 地址：吉林大学南胡校区
  • 邮编：130012
  • 邮箱：cjcu@jlu.edu.cn
  • 电话：0431-88499216
  • 国际标准刊号：ISSN：0251-0790
  • 国内统一刊号：ISSN：22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:50676