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Double-layer Modifi cation of Water-based Aluminum with SiO2 and Polyacrylic Acid by Solgel Process and in situ Polymerization
  • ISSN号:1000-2413
  • 期刊名称:《武汉理工大学学报:材料科学英文版》
  • 分类:TQ314.253[化学工程—高聚物工业] O632.51[理学—高分子化学;理学—化学]
  • 作者机构:School ofPrintingandPackaging, Wuhan University, Wuhan 430072, China
  • 相关基金:Funded by the National Natural Science Foundation of China(31170558); the Fundamental Research Funds for the Central Universities(410500006)
中文摘要:

由一个铝核心和 SiO 2 和 polyacrylic 酸的壳组成的双层铝被综合。这修改的铝被用来在水运的媒介改进腐蚀抵抗和铝的散性质。TEM, FTIR, XPS,和 EDX 决心证明泛美航空公司和 SiO 2 在铝的表面上是涂的。发展的氢察觉证明合成粒子的腐蚀抵抗显著地被改进了。SiO 2 的最大的腐蚀抑制效率涂的铝(当时, SiO 2@Al) 是 95.1% 双层的涂的铝(PAA/SiO 2@Al) 是 98.8% 。同时, polyacrylic 酸层显著地改进了铝的凝块。根据可分散性测试, 50% 体积部分的粒子尺寸[d (0.5 )] 铝, SiO 2@Al 和 PAA/SiO, 2@Al 分别地是 42, 53,和 34 m。

英文摘要:

A double-layer aluminum consisting of an aluminum core and a shellof SiO2 and polyacrylic acid was synthesized.This modified aluminum was used to improve the corrosion resistance and dispersive property of aluminum in waterborne media.TEM,FTIR,XPS,and EDX determination showed that PAA and SiO2 were coated on the surface of aluminum.Evolved hydrogen detection showed that the corrosion resistance of composite particle had been markedly improved.Maximum corrosion inhibition efficiency of SiO2 coated aluminum(SiO2@Al)was 95.1% while that of double-layer coated aluminum(PAA/SiO2@Al)was 98.8%.Meanwhile,polyacrylic acid layer improved the agglomeration of aluminum significantly.According to the dispersibility test,the particle size of 50% volume fraction [d(0.5)] of aluminum,SiO2@Aland PAA/SiO2@Alwere 42,53,and 34 μm,respectively.

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期刊信息
  • 《武汉理工大学学报:材料科学英文版》
  • 中国科技核心期刊
  • 主管单位:
  • 主办单位:武汉理工大学
  • 主编:
  • 地址:武汉市洪山区珞狮路122号
  • 邮编:430070
  • 邮箱:jwutms@mail.whut.edu.cn
  • 电话:027-87384113 87651870
  • 国际标准刊号:ISSN:1000-2413
  • 国内统一刊号:ISSN:42-1680/TB
  • 邮发代号:38-78
  • 获奖情况:
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  • 被引量:149