在两亲性聚合物的自组装领域,结晶驱动自组装因其内容的丰富性和较高的可塑性而被特殊看待。在经典的自组装体系中,要制备纤维状胶束相对比较困难,而结晶驱动自组装却能够很轻易地得到纤维状胶束并实现纤维的组成、长度及长度分布控制。其中,可结晶嵌段的结晶性被认为是形成纤维状胶束的关键并被进一步跟进拓展。
In the field of self-assembly of amphiphilic polymers,crystallization-driven self-assembly draws special attentions because of its richness in content and high mold ability.Cylindrical micelles with controllable compositions,length and distribution,which are difficult to obtain in conventional selfassembly systems,are highly available using crystallization-driven self-assembly.The crystallinity in copolymers is considered the key to the formation of cylindrical micelles and is widely studied.