位置:成果数据库 > 期刊 > 期刊详情页
Amidoxime-based adsorbents prepared by cografting acrylic acid with acrylonitrile onto HDPE fiber for the recovery of uranium from seawater
  • ISSN号:1000-3436
  • 期刊名称:《辐射研究与辐射工艺学报》
  • 时间:0
  • 分类:TL[核科学技术]
  • 作者机构:[1]Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China, [2]Nuclear and Radiation Safety Center, Ministry of Environmental Protection of the People’s Republic of China,Beijing 100035, China
  • 相关基金:This work was supported by the National Natural Science Foundation of China (Nos. 21676291, 21306220, 11275252, 11305243 and 11405249). The research was also in part supported by the ‘‘Knowledge Innovation Program of Chinese academy of sciences’’.
中文摘要:

An amidoxime-based polymeric adsorbent was prepared by pre-irradiation grafting of acrylonitrile and acrylic acid onto high-density polyethylene fibers using electron beams, followed by amidoximation. Quantitative recovery of uranium was investigated by flow-through experiment using simulated seawater and marine test in natural seawater. The maximum amount of uranium uptake was 2.51 mg/g-ads after 42 days of contact with simulated seawater and 0.13 mg/g-ads for 15 days of contact with natural seawater. A lower uranium uptake in marine test can be attributed to the short adsorption time and the contamination of marine microorganisms and iron. However,the high selectivity toward uranium against vanadium may be beneficial to harvest uranyl ion onto adsorbents and the economic feasibility for recovery of uranium from seawater.

英文摘要:

An amidoxime-based polymeric adsorbent was prepared by pre-irradiation grafting of acrylonitrile and acrylic acid onto high-density polyethylene fibers using electron beams, followed by amidoximation. Quantitative recovery of uranium was investigated by flow-through experiment using simulated seawater and marine test in natural seawater. The maximum amount of uranium uptake was 2.51?mg/g-ads after 42?days of contact with simulated seawater and 0.13?mg/g-ads for 15?days of contact with natural seawater. A lower uranium uptake in marine test can be attributed to the short adsorption time and the contamination of marine microorganisms and iron. However, the high selectivity toward uranium against vanadium may be beneficial to harvest uranyl ion onto adsorbents and the economic feasibility for recovery of uranium from seawater.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《辐射研究与辐射工艺学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院上海应用物理研究所
  • 主编:李景烨
  • 地址:上海市嘉罗公路2019号
  • 邮编:201800
  • 邮箱:lhb@sinap.ac.cn
  • 电话:021-59557478
  • 国际标准刊号:ISSN:1000-3436
  • 国内统一刊号:ISSN:31-1258/TL
  • 邮发代号:4-403
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:3553