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冷却速率对奥氏体不锈钢凝固过程影响的原位观察
  • ISSN号:1001-053X
  • 期刊名称:北京科技大学学报
  • 时间:2012
  • 页码:530-534
  • 分类:TF771.1[冶金工程—钢铁冶金]
  • 作者机构:[1]北京科技大学冶金与生态工程学院,北京100083, [2]北京科技大学材料科学与工程学院,北京100083
  • 相关基金:国家自然科学基金资助项目(50434040)
  • 相关项目:高性能中厚板钢中微小氧化物夹杂在凝固前沿行为研究
中文摘要:

通过采用激光共聚焦扫描显微镜对AISI304奥氏体不锈钢的凝固过程进行了原位动态观察研究.发现当冷却速率为0.05℃.s-1时,奥氏体不锈钢以胞状晶方式凝固,其凝固模式为FA模式,即δ铁素体相先从液相中形核并长大,γ相在1 448.9℃时通过与液相发生包晶反应(L+δ→γ)在δ铁素体相界形成,当温度降到1 431.3℃时液相消失,δ铁素体相通过固态相变转变为γ相,富Cr贫Ni的残留铁素体位于胞状晶之间.当冷却速率为3.0℃.s-1时,奥氏体不锈钢以枝晶方式生长,冷却到1346.4℃时包晶反应在液相与δ铁素体相界之间进行,其残留铁素体位于枝晶干,与冷却速率为0.05℃.s-1时相比,其残留铁素体的数量增多,残留铁素体富Cr贫Ni的程度减轻.

英文摘要:

Solidification processes of AISI304 austenitic stainless steel at cooling rates of 0.05℃.s-1 and 3.0 ℃.s-1 were observed in situ by confocal laser scanning microscopy. When the cooling rate is 0. 05 ℃.s-1 the solidification front is cellular morphology and the solidification mode belongs to FA mode. B ferrite appears firstly in liquid steel, and then γ phase precipitates prior at B-grain boundaries at 1 448.9℃ by means of the periteetic reaction (L+δ→γ). At 1 431.3 ℃ the liquid steel disappears. Finally the B ferrite transforms to γ phase by solid diffusion, and the retained ferrite which enriches in Cr and depletes in Ni locates between the cellular dendrites. When the cooling rate is 3.0℃.s-1 , the solidification interface morphology is dendritic. The peritectic reaction takes place at interfaces between B-grains and the remained liquid at 1 346.4 ℃, and the retained ferrite locates in the dendrite arm. Compared to 0.05℃.s-1 , the degree of enrichment in Cr and depletion in Ni in the residual ferrite decreases but the amount of them increases.

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