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洗涤塔脱除燃烧源超细颗粒的实验研究
  • ISSN号:0438-1157
  • 期刊名称:化工学报
  • 时间:0
  • 页码:1508-1514
  • 语言:中文
  • 分类:X51[环境科学与工程—环境工程]
  • 作者机构:[1]东南大学洁净煤发电及燃烧技术教育部重点实验室,江苏南京210096
  • 相关基金:国家自然科学基金项目(20576020);国家重点基础研究专项经费项目(2002CB211604).
  • 相关项目:蒸汽相变促进燃烧源PM2.5凝结长大的研究
中文摘要:

在填料洗涤塔中进行了利用蒸汽相变原理促进燃煤和燃油超细颗粒凝结长大并高效脱除的实验研究;采用电称低压冲击器(ELPI)、SEM及XPS对两种燃烧源细颗粒凝结洗涤前后的数浓度、粒径分布、形貌和元素组分进行了分析测试,考察了洗涤塔进口气液温差、进口烟气含湿量及液气比等对脱除效率的影响。结果表明,燃煤和燃油产生的超细颗粒形貌和组分具有较大的差别,燃煤超细颗粒主要为硅铝矿物质,而燃油超细颗粒主要为含炭物质;在相同条件下,燃煤超细颗粒相变脱除效果优于燃油超细颗粒;脱除效率随洗涤塔进口气液温差的增大而提高,在相同进口气液温差下,增大进口烟气含湿量可显著提高超细颗粒的脱除效率;液气比的影响与填料洗涤塔内是否存在蒸汽相变有关;通过合理调节进口烟气含湿量及进口烟气与洗涤液的温差在填料塔内建立微粒凝结长大所需的过饱和水汽环境可有效脱除燃烧源超细颗粒。

英文摘要:

Packed column scrubber in which vapor condensation with fine particles acting as nucleation nuclei was used to separate fine particles from combustion.The particle size distributions and concentrations before and after scrubbing were measured by the electrical low pressure impactor (ELPI).The microstructure and major element compositions of fine particles were analyzed by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) respectively.Based on this, the influences of operating parameters, such as the temperature difference between gas and water at the inlet of scrubber, the moisture contents of flue gas, liquid to gas rate, on the particle removal efficiency were investigated.The results showed that the morphology and compositions of the fine particles from coal and oil combustion were very different.The fine particles from coal combustion mainly were mineral substances of Si and Al, while the particles from oil combustion mainly were carbon.The removal efficiency of fine particles from coal combustion was higher than that of oil under the same conditions.It was also found that the removal efficiency increased with increasing inlet temperature difference between gas and liquid.When the temperature difference was the same, the condensational removal efficiency could be highly enhanced with increasing humidity of inlet gas.The influence of liquid to gas ratio was related to the existence of heterogeneous condensation in the packed column scrubber.The result indicated that fine particles could be effectively removed by the packed column in which supersaturation of vapor and corresponding droplet growth by heterogeneous condensation were able to be achieved by adjusting the moisture contents of the inlet gas and the inlet temperature difference between flue gas and water.

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期刊信息
  • 《化工学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国化工学会 化学工业出版社
  • 主编:李静海
  • 地址:北京市东城区青年湖南街13号
  • 邮编:100011
  • 邮箱:hgxb126@126.com
  • 电话:010-64519485
  • 国际标准刊号:ISSN:0438-1157
  • 国内统一刊号:ISSN:11-1946/TQ
  • 邮发代号:2-370
  • 获奖情况:
  • 中国科协优秀期刊二等奖,化工部科技进步二等奖,北京全优期刊奖,中国期刊方阵“双效”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:35185