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烧结工艺颗粒物中水溶性离子排放特性分析
  • ISSN号:1000-6923
  • 期刊名称:《中国环境科学》
  • 时间:0
  • 分类:X513[环境科学与工程—环境工程]
  • 作者机构:南开大学环境科学与工程学院,国家环境保护城市空气颗粒物污染防治重点实验室,天津300071
  • 相关基金:国家自然科学基金项目(21407081,41205089); 天津市科技计划项目(14ZCDGSF00029)
中文摘要:

采用荷电低压颗粒物撞击器(ELPI)对两段烧结工艺经除尘、脱硫后排放的颗粒物进行采样,分析颗粒物的粒数和质量浓度以及颗粒物中所含水溶性离子的粒径分布特征.结果表明,烧结工艺经除尘、脱硫后颗粒物的粒数浓度在10-5-10-7cm^-3,粒径小于0.1μm的颗粒物占总粒数浓度的67%-77%.颗粒物质量浓度呈双峰分布,烧结1分别在0.61μm和1.62μm处出现峰值,烧结2分别在0.37μm和1.62μm处出现峰值;对不同粒径段颗粒物中的水溶性离子进行分析后表明,烧结1排放的PM1中含量最高的是NH4^+和Ca^2+,分别为15.26%和14.84%;PM〉1中含量最高的是SO4^2-,为33.52%.烧结2排放的PM1中含量最高的是Cl^-,为28.12%;PM〉1中含量最高的是SO4^2-,为29.21%.SO4^2-在烧结1中主要集中在6.89-10.23μm这一粗粒径段中,占60%左右,而在烧结2中主要集中在粒径小于2.5μm的细粒径段颗粒物中,占81%左右.Cl^-在烧结1不同粒径段颗粒物中含量较低且分布较均匀,而在烧结2中Cl^-在0.13-0.24μm粒径段颗粒物中出现峰值且含量较高达45%左右.

英文摘要:

Electrical low pressure impactor (ELPI) was used to analyze the particulate matters size, mass concentration distribution and ions from two sintering processes after dust removal and desulfurization. Results showed that the grain number concentration of the particulate matters from the sintering process after dust removal and desulfurization was in the range of 105-107cm3, and 67%-77% particulate matters' particle sizes were mainly below 0.1tam. The mass concentration distribution showed double peaks. Two peaks respectively existed at 0.611am and 1.621arn of particle size in No.lsintering process, while two peaks respectively existed at 0.37tun and 1.62tun of particle size in No.2 sintering process. Chemical composition analysis indicated that the highest content of water-soluble ions in PM1 from No.1 sintering process were NH4+ and Ca2+, which was 15.26% and 14.84%, respectively. The highest content of water-soluble ion in PM〉1 from No.1 sintering process was SO42, which was 33.52%. The highest content of water-soluble ions in PM1 and PM〉I from No.2 sintering process were Cl- and SO42-, which was 28.12% and 29.21%, respectively. 60% of SO42 concentrated in the particulate matters of 6.89-10.23μm particle size in No.lsintering process, and 81% of SO42 concentrated in the particulate matters with the particle size below 2.5μm in No.2 sintering process. The content of Cl- in the particulate matters of different particle sizes distributes uniformly in No.lsintering process, and 45% of Cl concentrated in the particulate matters of 0.13-0.241am particle size for a peak in No.2 sintering process.

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期刊信息
  • 《中国环境科学》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国环境科学学会
  • 主编:王文兴
  • 地址:北京市海淀区红联南村54号
  • 邮编:100082
  • 邮箱:zghjkx1981@126.com
  • 电话:010-62215145
  • 国际标准刊号:ISSN:1000-6923
  • 国内统一刊号:ISSN:11-2201/X
  • 邮发代号:2-572
  • 获奖情况:
  • 国家期刊提名奖,国家“双效”期刊,第三届中国科协优秀科技期刊一等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国科学文摘数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:47702