利用分子束外延法在MgO(100)衬底上制备Bi2.1CaySr1.9-yCuO6+δ薄膜。薄膜的结构、外延性、化学计量比及表面形貌通过X射线衍射仪、X射线能谱仪及扫描电子显微镜表征,薄膜的R-T曲线通过标准四引线法测量。结果表明,Bi2.1CaySr1.9-yCuO6+δ薄膜具有较好的结晶性能,沿衬底[001]方向c轴外延生长,且表面平整;随Ca含量(0.2≤y≤1.0)不同,Bi2.1CaySr1.9-yCuO6+δ相的c轴长度发生变化,且薄膜显现不同的导电特性。
The Bi2.1CaySr1.9-yCuO6+δ thin films with c-axis oriented epitaxial were deposited on MgO (100) substrates by moleculor beam epitaxy (MBE) method. The film properties of structure, composition and surface morphology were investigated by X-ray diffraction (XRD), X-ray energy dispersive spectrometry (EDS) and scanning electron microscopy (SEM), respectively. Temperature dependence of resistance (R-T) was measured by the standard four-probe method. It demonstrates that the Bi2.1CaySr1.9-yCuO6+δ thin films are fabricated owning a good crystalline quality, c-axis epitaxial growth and smooth surface. The c-axis length of Bi2.1CaySr1.9-yCuO6+δ phase and the conductibility of thin films are varied with Ca doping (0.2≤y≤1.0).