通过实验室模拟研究不同湿法存放时间(1~60个月)的2种低钙粉煤灰的形貌、粒径和用于混凝土掺合料的性能变化。粉煤灰湿排后颗粒变粗,颗粒表面出现侵蚀,但颗粒形貌基本保持不变;湿排粉煤灰矿物减水效应明显降低,掺量为20%~40%的湿排粉煤灰混凝土坍落度比原状粉煤灰混凝土减少约20~40mm;掺加湿排粉煤灰的混凝土与外加剂适应性、抗渗和抗碳化无明显变化,坍落度经时损失有所降低;湿法存放3个月的粉煤灰掺量20%时混凝土28d和56d抗压强度比原状粉煤灰混凝土分别下降5.8%和3.7%,但掺量为20%的湿法存放36个月粉煤灰混凝土抗压强度比仍可以达到85%,湿法存放时间为3a和5a的粉煤灰混凝土强度无明显差别。研究结果表明,湿排低钙粉煤灰可以用作为混凝土掺合料。
Two types of wetting low-calcium fly ash were made for studying the performance under different storage time (1 to 60 months). The surface morphology, granule size distribution of the wetting fly ashes and their properties as supplementary cementitious materials in concrete were investigated. Although the granule size increased and there appeared considerable erosion on the surface, the surface morphology of wetting fly ash kept mostly unchangeable. The water reducing effect resulted from mineral properties of fly ash decreased much due to wetting. Compared with a parallel concrete with dry fly ash, slump of concretes with fly ash of 20-40% wetting for 3 months decreased by 20-40 mm while bleeding and permeability and carbonation had no change. The compressive strength of concrete in 28 day and 60 days with fly ash of 30% wetting for 3 months decreased by 5. 8% and 3. 7% respectively. However, the specific compressive strength of concrete in 56 days with fly ash of 20% wetting for 36 months still reached at 85% and there was no visible strength discrepancy of fly ash concrete wetting for 3 and 5 years. It was concluded that a wetting low-calcium fly ash could be used as supplementary cementitious material in some important concretes.