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后处理对改性聚氨酯系中空纤维膜压力响应行为的影响
  • ISSN号:0438-1157
  • 期刊名称:《化工学报》
  • 时间:0
  • 分类:TQ323.8[化学工程—合成树脂塑料工业] TQ028.8
  • 作者机构:[1]天津工业大学中空纤维膜材料与膜过程省部共建国家重点实验室培育基地,天津300160
  • 相关基金:国家重点基础研究发展计划项目(2012CB722706);国家自然科学基金项目(20874073);天津市科技计划项目(10SYSYJC27900).
中文摘要:

采用熔融纺丝制得改性聚氨酯系中空纤维膜,通过测试水通量随压力的变化研究了拉伸、热处理温度和热处理时间对改性聚氨酯系中空纤维膜压力响应行为的影响。结果表明,所得膜可发生明显的压力响应行为,且拉伸倍数越大,膜的强度越大,压力响应行为越精确;随热处理温度升高,膜的支撑性变差,压力响应行为变弱;随热处理时间延长,膜形变回复率变低,压力响应行为减弱。

英文摘要:

Modified polyurethane (PU) based hollow fiber membranes were prepared by the melt-spinning method. Influences of drawing, heat treatment temperature and heat-treatment time on the pressure- responsive behavior were studied by the relationships between water flux and test pressure. The results showed that the hollow fiber membranes exhibited obvious pressure-responsive behavior. With increasing theoretical draw ratio, the strength of the membrane was greater and the pressure-responsive behavior was stronger. While, membrane pore size on inner surface and mean pore size became larger, the pure water flux (PWF) increased, the porosity first increased then slightly decreased. With increasing heat-treatment temperature, membrane support became worse and the pressure-responsive behavior became weaker. While, membrane pore size became smaller, the PWF and porosity of membrane increased and then decreased. With extending heat-treatment times, the deformation-recovery ratio of membrane diminished and the pressure-responsive behavior became weaker. The PWF and porosity of membrane first increased, then decreased, finally achieved stability.

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期刊信息
  • 《化工学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国化工学会 化学工业出版社
  • 主编:李静海
  • 地址:北京市东城区青年湖南街13号
  • 邮编:100011
  • 邮箱:hgxb126@126.com
  • 电话:010-64519485
  • 国际标准刊号:ISSN:0438-1157
  • 国内统一刊号:ISSN:11-1946/TQ
  • 邮发代号:2-370
  • 获奖情况:
  • 中国科协优秀期刊二等奖,化工部科技进步二等奖,北京全优期刊奖,中国期刊方阵“双效”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:35185