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聚氨酯系中空纤维膜压力响应行为研究
  • 期刊名称:功能材料
  • 时间:0
  • 页码:2027-2030
  • 语言:中文
  • 分类:TQ028.8[化学工程]
  • 作者机构:[1]天津工业大学中空纤维膜材料与膜过程教育部重点实验室,天津300160, [2]天津工业大学材料科学与工程学院,天津300160
  • 相关基金:国家自然科学基金资助项目(20874073);国家高技术研究发展计划(863计划)资助项目(2007AA030304);天津市科技支撑计划重点资助项目(08ZCGYGX03700)
  • 相关项目:熔融纺丝法压力响应功能中空纤维膜研究
中文摘要:

研究了熔融纺丝法聚氨酯(PU)系中空纤维膜的压力响应性。结合σ-λ曲线,采用二参数Mooney-Rivlin模型对后拉伸8倍中空纤维膜的压力响应性进行了有限元模拟。结果表明,所得模型在透膜压力低于0.1MPa时与实测数据吻合较好,而高于0.1MPa时与实测数据出现较大差异。分析结果表明,当透膜压力高于0.1MPa时,中空纤维膜在压力响应过程中在微孔孔径发生改变的同时孔数量也发生了变化。

英文摘要:

The pressure responsibility of the PU-based hollow fiber membrane was studied. According to the σ-λ curves, the finite element simulation of the pressure responsibility of the hollow fiber membrane after stretching 8 times was done using the two-parameter Mooney-Rivlin model. Results showed that the theoretical curve matched the real one under 0.1PMa while the real one became much higher after 0.1MPa. It could be analyzed that during pressure responsible processes, both the quantities and the size of the microvoids changed when the trans-pressure was more than 0.1MPa.

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