中文摘要：

二苄基二氯化锡和三苄基氯化锡分别与水杨醛缩氨基硫脲，含羟基芳香醛（酮）缩氨基硫脲的席夫碱钠盐反应，合成了10种新的有机锡配合物，其结构经^1H NMR，^119Sn NMR，IR和元素分析表征。结果表明．中心锡原子均为五配位杂单环结构。

英文摘要：

Ten new organotin complexes were synthesized by the reactions of di- and tribenzyltin chloride with corresponding sodium salts of salicylaldehyde thiosemicarbazone, o-vanillin thiosemicarbazone, 2,4-dihydroxybenzaldehyde thiosemicarbazone, 2,4-dihydroxyacetophenone thiosemicarbazone and o-hydroxyacetophenon thiosemicarbazone. Their structures were characterized by ^1H NMR, ^119Sn NMR, IR and elemental analysis. The results showed that the central metal, Sn, was heterecyclic pentacoordinative.