中文摘要：

以2-甲基苯并眯唑为原料，合成了一个新型的苯并咪唑二羧酸衍生物，基结构通过IR，^1HNMR，元素分析和X-射线单晶衍射法确定。X射线衍射单晶结构分析表明，固态时标题化合物通过分子间氢键形成一维无限链状结构，这些一维无限链状结构又通过链与链间的苯并眯唑环的π-π堆积作用形成二维结构。标题化合物的晶体属单斜晶系，P21／c空间群；Mr：568．54，a=19．821（3），b=7，．4501（11），c=20．093（3）A，B；116．479（3）°，v=2655．8（3）A^3，z=4，Dc=1．422mg·m^3F（000）=1200，最终偏离因子R=0．0675，wR=0．2187。

英文摘要：

The title compound,N,N＇-dicarboxymethyl-2-metbylbenzimidazole,was synthesized from the starting material of 2-methylbenzimidazole. Its structure was detemined by IR, ^1H NMR,elemental analysis and X-ray diffraction. X-ray analysis revealed that one-dimensional polymeric structures in the solid State were formed by intermoleeular hydrogen bonds between the title compounds , and these polymers were further extended into two-dimensional structure by π-π stacking interaction between benzimidazole rings. The crystal was monoclinic system with space group P21/c, Mr ：568.54, a = 19. 821 （ 3 ）, b = 7. 4501 （ 11 ）, c = 20. 093 （ 3 ） A,β = 116.479（3）° ,V =2655.8（3） ]k3 ,z =4,Do = 1. 422mg·m^3 ,F（000） = 1200,R =0.0675 ,wR =0.2187.