在氧存在下以NH3为还原剂的选择性催化还原烟气NOX技术(SCR)已经工程化。工业中常用的催化剂,主要是V2O5/TiO2或V2O5-WO3/TiO2,在300℃~400℃表现出高的NOX脱除率。为此,选择性催化还原法(SCR)装置须安装在空气预热器之前和省煤器之后,以利用过程的烟气温度。但这里存在的高浓度粉尘和SO2容易引起催化剂中毒和使用寿命减少,因此,研究开发低温运行(〈300℃)的SCR催化剂,使催化反应器能布置在除尘或/和脱硫之后,具有重要意义。同时烟道废气的温度会因生产装置负荷的变化而有较大的波动,这就要求催化剂具有较宽的高活性温度区间。
The selective catalytic reduction (SCR) of NOx using MnOx and CeO2 supported on viscose-based active carbon fibers (ACF) at 120℃ -270℃ relatively lower than the temperature when using V2O5/TiO2-anatase catalyst was studied. As a result, CeO2/ACF shows a better catalysis than MNOx/ACF, which is not affected by the reaction temperature. NO conversion of 85% is reached with the 10% -CeO2/ACF catalyst at the whole temperature window. Furthermore, a series of MnOx-CeO2/ACF composite catalysts were studied. The results show that the loading method of catalyst affects its activity .