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Ligand assisted copper-catalyzed Ullmann cross coupling reaction of bromaminic acid with amines
  • ISSN号:1004-9541
  • 期刊名称:《中国化学工程学报:英文版》
  • 时间:0
  • 分类:O621.251[理学—有机化学;理学—化学] O641.4[理学—物理化学;理学—化学]
  • 作者机构:State Key Laboratory of Fine Chemicals, Dalian University of Technology
  • 相关基金:Supported by the National Natural Science Foundation of China(21176038,21576044,21536002);the Science Fund for Creative Research Groups of the National Natural Science Foundation of China(21421005);the Dalian University of Technology Innovation Team(DUT2013TB07)
中文摘要:

Three types of ligands have been developed for copper-catalyzed Ullmann cross coupling reaction of bromaminic acid with amines in aqueous solution. Ligands with large steric hindrance and strong electron-donating capacity were beneficial to the reaction. UV–Vis and CV analyses demonstrated that these ligands had strong coordination with copper(I), implying the effect of ligand coordination ability on the stability and catalytic activity of catalytic system.

英文摘要:

Three types of ligands have been developed for copper-catalyzed Ullmann cross coupling reaction of bromaminic acid with amines in aqueous solution. Ligands with large steric hindrance and strong electron-donating capacity were beneficial to the reaction. UV-Vis and CV analyses demonstrated that these ligands had strong coordination with copper(I), implying the effect of ligand coordination ability on the stability and catalytic activity of catalytic system. (C) 2016 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.

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期刊信息
  • 《中国化学工程学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国化学工业与化学工程学会
  • 主编:
  • 地址:北京东城区青年湖路13号
  • 邮编:100011
  • 邮箱:cjche@cip.com.cn
  • 电话:010-64519487/88
  • 国际标准刊号:ISSN:1004-9541
  • 国内统一刊号:ISSN:11-3270/TQ
  • 邮发代号:
  • 获奖情况:
  • 1998年化工系统优秀信息成果一等奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
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  • 被引量:385