以相对论多体微扰理论为基础,利用屏蔽理论的思想和方法,引入并改进了与核电荷数Z相关的能量修正函数,计算了C工等电子序列离子(6≤Z≤55)基组态(1s^22s^22p^2)和第一激发态(1s^22s^22p^1)能量.计算过程基于自编的C语言和MATLAB程序,所得结果与实验值符合得很好,大大减小了由于忽略能量高阶项产生的误差,证明此项改进适用于等电子序列离子组态能量的计算.
Based on the relativistic many-body perturbation theory(RMBPT) and screening theory for many electron atomic system, the energies of C-like sequence ions( 6 ≤ Z ≤ 55 ) for ground configuration( 1s^22s^22p^2 ) and the first excited configuration( 1s^22s^22p^1 ) are calculated. An improved Z-dependent modify function is introduced to increase the accuracy of the result, which makes it excellent agree with the available experimental data. C and MATLAB programs are designed for this calculation. The conclusion is obtained that this modification is suitable for the calculation of the configuration energies of isoelectronic sequence ions.