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胶体晶体制备与应用研究进展
  • ISSN号：0023-074X
  • 期刊名称：科学通报
  • 时间：2014
  • 页码：752-762
  • 分类：TQ224.6[化学工程—有机化工]
  • 作者机构：中国石油大学(华东)重质油国家重点实验室,山东青岛266580
  • 相关基金：国家自然科学基金项目（No.51172284）,中央高校基本科研业务费专项资金（No.15CX06048A）资助项目
  • 相关项目：基于液/冰界面自组装制备高分子通透结构有序多孔薄膜的研究
作者： 于冰|丛海林|薛蕾|刘学松|陈昭晶|
关键词： 乙醇醛, 甲醛, 氢甲酰化, formose反应, N-杂环卡宾, glycolaldehyde, formaldehyde, hydroformylation, formose reaction, N-heterocyclic carbene
中文摘要：

介绍了乙醇醛作为中间体在食品、医药卫生和化工等行业的应用。综述了以甲醛为原料生产乙醇醛的工艺,包括氢甲酰化反应;高选择性的formose反应;通过典型的formose反应制备糖醇,再含水热解;N-杂环卡宾催化。指出N-杂环卡宾催化甲醛合成乙醇醛是最具前景的生产策略,值得深入研究。

英文摘要：

Glycolaldehyde is an intermediate to produce high value-added products and can be used in food, medicine, hygiene and chemical industry. The paper summarizes the synthesis of glycolaldehyde, including hydroformylation of formaldehyde, selective formose reaction, hydrous thermolysis of sugar alcohols produced by typical formose reaction and N-heterocyclic carbene catalysis. Each process is reviewed. It is pointed out that N-heterocyclic carbene catalysis is the most promising production strategy, which is worthy of further research.

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期刊信息
  • 《科学通报》
  • 北大核心期刊（2011版）
  • 主管单位:中国科学院
  • 主办单位:中国科学院
  • 主编：周光召
  • 地址：北京东黄城根北街16号
  • 邮编：100717
  • 邮箱：csb@scichina.org
  • 电话：010-64036120 64012686
  • 国际标准刊号：ISSN：0023-074X
  • 国内统一刊号：ISSN：11-1784/N
  • 邮发代号:80-213
  • 获奖情况:
  • 首届国家期刊奖,中国期刊方阵“双高”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,美国数学评论（网络版）,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:81792