中文摘要：

采用饱和蒸气扩散技术,将2,4-二羟基苯甲醛缩异烟酰腙（H2dhbi）配体分别与Zn（ClO4）2·6H2O和Zn（NO3）2·6H2O进行配位作用,得到2种不同配位模式的金属-有机框架材料[（dhbi）2Zn2·8H2O]n（1）和{[（dhbi）2（H2O）2Zn2]·4DMF]}n（2）.利用X射线单晶衍射、热分析技术（TG-DTA）和X射线粉末衍射（PXRD）等方法进行了结构表征.进一步将配位聚合物1和2用于对甲醇分子的吸附性能研究,结果表明,化合物1是一种理想的微孔材料,其对甲醇分子的吸附能力为化合物2的近5倍,采用PLATON对材料的孔隙体积进行计算得到化合物1和2的孔隙率分别为38.2%和5.5%.

英文摘要：

By employing the N＇-（ 2,4-dihydroxybenzylidene）-isonicotinohydrazide ligand to assemble with zinc ions in different solvents,the two metal-organic frameworks（ MOFs） 1 and 2 were obtained,namely[（ dhbi）2Zn2·8H2O]n（ 1） was obtained from the ligand assemble with Zn（ ClO4）2·6H2O,{ [（ dhbi）2（ H2O）2Zn2]·4DMF]}n（ 2） was obtained from the ligand assemble with Zn（ NO3）2· 6H2O using diffusion technology of saturated vapor. Single crystal diffraction was used to characterize their structures.Thermogravimetric analysis（ TG-DTA） and powder X-ray diffraction（ PXRD） were used to measure their thermal stability and purity. The results of vapor adsorption for Me OH indicate that complex 1 is a kind of satisfactory microporous material,further the complex 1 shows 38. 1% void volume,and the complex 2 shows 5. 5%void volume according to PLATON calculations.